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习题练习:What Drives Chemical Reactions D.4 Entropy and Spontaneity



 作者: admin   总分: 14分  得分: _____________

答题人: 匿名未登录  开始时间: 23年07月23日 17:22  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following reactions will have the greatest decreagf-b. y3ibjsf/ vw09p0u hr5sxe )mf1se in entropy?

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following combinations of ΔH ioovm0 9dy / wu;c,+gband ΔS results in the most spontaneous reaction at 2990wmgbd,iucov+ /o; y8 K?

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following statements about enth6ke.0dd- c zn5m9akwropy is incorrect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following compounds are akx t0)w6*c9g j7hdg.sueh ue :rranged in order of decreasing entropy?

$C$(s)
$H_2O$(l)
$O_2$
$CO_2$(g)
>

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is true for an endothp 1:xqj vd-)jx.d,t j b1hhj*zermic reaction that results in an increase in entrodp*)1xtjjh-bjd,1 qx : hz. jvpy?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about the relationshi :sbxt 9iw/1t,ya fu7np between Gibbs free energy change and the equilibu,:7xb9iywatsn/ 1tfrium constant is correct?

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following factors affec;tao 159(bakbg5nc1r-jn* cge rk )wht the entropy of a system containing gases? - b)n rn1bwhgkct ega5o;1j5a(kc9 *r
I. The temperature of the system
II. The states of the system
III. The pressure of the system

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8#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Gibbs free energy change can be used to determine the spontok /5w xhq1y2sl;vmnh ,8z6e oaneity of a reactiovlxz8n ,/m5w yhe26o ;q skho1n.
1.1.Define Gibbs free energy change of formation.
1.2.Define spontaneous reaction.

2.1.State a correctly balanced equation that represents the complete combustion of butane.

2.2.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the Gibbs free energy change of this reaction.
ΔG$_{reaction}$=-  kJ mol$^{-1}$
2.3.State, with a reason, whether this reaction is spontaneous or not.

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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9#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Methanol is produced by reacting carboeop * m/ lx/15oc-cwgt0n(bfb n monoxide and hydrogen according to the following rea1n mbbf0(g /5*oxc/wocelp-tction:
$CO(g)$+2$H_2(g)$ → $CH_3OH$(g)
$CO(g)$+2$H_2(g)$ ← $CH_3OH$(g)
1.Deduce the equilibrium constant expression for the formation of methanol.
At 500$^{\circ}C$ ,a 750cm$^3$ sealed flask is found to contain 0.923 mol of CH_3OH, 0.352mol of CO and 0.124 mol of $H_2$.
2.1.Calculate the value of K$_c$ at 500 $^{\circ}C$. K$_c$=  
2.2.Using sections 1 and 2 of the data booklet, calculate ΔG$^θ$ at 500 $^{\circ}C$.
T=  K;ΔG$^θ$=-  kJ mol$^{-1}$

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Ethanol can be produced through tda nbsd9((;ug4jk g i5 a)y,jphe fermentation of glucose:
$C_6H_12O_6$(aq)→2$C_2H_5OH$(l)+2$CO_2$(g)
1.1.Predict whether the entropy change for this reaction is positive or negative. Explain your reasoning.
1.2.The absolute entropy for glucose is +209.2 J K$^{-1}$ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change for this reaction.
ΔS$_{reaction}$=+  JK$^{-1}$ mol$^{-1}$

2.The enthalpy of formation of glucose is -1273.3kJ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the enthalpy change for this reaction.
ΔH$_{reaction}$=-  kJ mol$^{-1}$

3.Using your answers to (a)(ii) and (b), calculate the Gibbs free energy change at 298K.
ΔG=-  kJ mol$^{-1}$
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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11#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Dry ice, solid $CO_2$,is commonly used as a cooling or freezing agent in the medical and food industries.
1.Write an equation representing the sublimation of $CO_2$.
2.The enthalpy of sublimation for $CO_2$ is +26.1kJ mol$^{-1}$ and the absolute entropy of $CO_2$ in the solid state is 51.1 J K$^{-1}$ mol$^{-1}$.
2.1.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change associated with the sublimation of $CO_2$.
ΔS$_{reaction}$=+  J K$^{-1}$ mol$^{-1}$
2.2.Using your answer to (bi), calculate the Gibbs free energy change for the sublimation of $CO_2$ at K.
ΔG=-  kJ mol$^{-1}$

3.Calculate the minimum temperature at which $CO_2$ sublimates.
T>  K

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  How does Gibbs free energy relate toua3 d x 7jamsw22vn:,c chemical equilibrium?

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13#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the followinqw(pkeal*m8h rwgp8 ej43z 4- g reaction:
$C_2H_4$(g)+$H_2$(g)→$C_2H_6$(g)
ΔH is -136kJ mol$^{-1}$
ΔS is -121jk$^{-1}$ mol$^{-1}$
ΔG at 298K is -99.9kJ mol$^{-1}$
1.1.Explain why the enthalpy of formation of $H_2$ is 0 kJ mol$^{-1}$.
1.2.Explain why the entropy change for this reaction is negative.

2.Explain how a reaction can be spontaneous with a negative entropy change.

3.Calculate the temperature at which this reaction is no longer spontaneous.
T=  K

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The following graph shows the Gibbs free energy against the ex +4*skpa n1aystent of reaction for a reversible y*a4n k+s1a spreaction.
At what point is the reaction at equilibrium?




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