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习题练习:What Drives Chemical Reactions D.4 Entropy and Spontaneity



 作者: admin   总分: 14分  得分: _____________

答题人: 匿名未登录  开始时间: 23年07月23日 17:22  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following reactions will have the greatest decrease 5 jg-gbg8/af9o8 ikulin entropy?

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following coycbubz69nyk8 * g*.lombinations of ΔH and ΔS results in the most spontaneous reaction ay b.6*9gb8 nclokz y*ut 298 K?

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the followi842yb 9t i -dgdjja(ymng statements about entropy is incorrect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following compoundt jv0hqy ,if864aeo :ms are arranged in order of decreasing entropy?

$C$(s)
$H_2O$(l)
$O_2$
$CO_2$(g)
>

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is true for an endothermic reaction that results in an incr pj jig150w6y7luxj5 du1 2ulaease in enaj 7xypj i2udl w 6jg5l50uu11tropy?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about the relationship between Gibbs free exr; v pf; :i/tla29xaloc6r(mnergy change and the equilibrium constant ifvila tcal xrm(ro9x 6p;2:/; s correct?

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following factors affect the entropy of a system coa e yoto+n5(7hju(k*r i(+x mtntaining gases? +jknh7 *yeua m5 ((ixoo rt(t+
I. The temperature of the system
II. The states of the system
III. The pressure of the system

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8#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Gibbs free energy change can be usy;*dcpv+ su)*r.v vdbj9*bc ked to determine the spontaneity of a reacticvdsbv .d kj9v;y*buc* *+p) ron.
1.1.Define Gibbs free energy change of formation.
1.2.Define spontaneous reaction.

2.1.State a correctly balanced equation that represents the complete combustion of butane.

2.2.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the Gibbs free energy change of this reaction.
ΔG$_{reaction}$=-  kJ mol$^{-1}$
2.3.State, with a reason, whether this reaction is spontaneous or not.

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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9#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Methanol is produced by reacting cgbox z4 0la76carbon monoxide and hydrogen according to the followizo0a67 lbxc 4gng reaction:
$CO(g)$+2$H_2(g)$ → $CH_3OH$(g)
$CO(g)$+2$H_2(g)$ ← $CH_3OH$(g)
1.Deduce the equilibrium constant expression for the formation of methanol.
At 500$^{\circ}C$ ,a 750cm$^3$ sealed flask is found to contain 0.923 mol of CH_3OH, 0.352mol of CO and 0.124 mol of $H_2$.
2.1.Calculate the value of K$_c$ at 500 $^{\circ}C$. K$_c$=  
2.2.Using sections 1 and 2 of the data booklet, calculate ΔG$^θ$ at 500 $^{\circ}C$.
T=  K;ΔG$^θ$=-  kJ mol$^{-1}$

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Ethanol can be produced thrt0;xm+y8r+ gv o;mgcoough the fermentation of glucose:
$C_6H_12O_6$(aq)→2$C_2H_5OH$(l)+2$CO_2$(g)
1.1.Predict whether the entropy change for this reaction is positive or negative. Explain your reasoning.
1.2.The absolute entropy for glucose is +209.2 J K$^{-1}$ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change for this reaction.
ΔS$_{reaction}$=+  JK$^{-1}$ mol$^{-1}$

2.The enthalpy of formation of glucose is -1273.3kJ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the enthalpy change for this reaction.
ΔH$_{reaction}$=-  kJ mol$^{-1}$

3.Using your answers to (a)(ii) and (b), calculate the Gibbs free energy change at 298K.
ΔG=-  kJ mol$^{-1}$
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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11#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Dry ice, solid $CO_2$,is commonly used as a cooling or freezing agent in the medical and food industries.
1.Write an equation representing the sublimation of $CO_2$.
2.The enthalpy of sublimation for $CO_2$ is +26.1kJ mol$^{-1}$ and the absolute entropy of $CO_2$ in the solid state is 51.1 J K$^{-1}$ mol$^{-1}$.
2.1.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change associated with the sublimation of $CO_2$.
ΔS$_{reaction}$=+  J K$^{-1}$ mol$^{-1}$
2.2.Using your answer to (bi), calculate the Gibbs free energy change for the sublimation of $CO_2$ at K.
ΔG=-  kJ mol$^{-1}$

3.Calculate the minimum temperature at which $CO_2$ sublimates.
T>  K

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  How does Gibbs free eb,/ a+0 4z 1uieh2bagrh oae1energy relate to chemical equilibrium?

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13#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reac.)-0 s gh0tffyx yn7axtion:
$C_2H_4$(g)+$H_2$(g)→$C_2H_6$(g)
ΔH is -136kJ mol$^{-1}$
ΔS is -121jk$^{-1}$ mol$^{-1}$
ΔG at 298K is -99.9kJ mol$^{-1}$
1.1.Explain why the enthalpy of formation of $H_2$ is 0 kJ mol$^{-1}$.
1.2.Explain why the entropy change for this reaction is negative.

2.Explain how a reaction can be spontaneous with a negative entropy change.

3.Calculate the temperature at which this reaction is no longer spontaneous.
T=  K

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The following graph shows the Gibbs free energy against the extent of:iii( or-)hnh 5fm cn/ reaction for a reversible )onh fi(/ihrm5-: icn reaction.
At what point is the reaction at equilibrium?




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