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习题练习:What Drives Chemical Reactions D.4 Entropy and Spontaneity



 作者: admin   总分: 14分  得分: _____________

答题人: 匿名未登录  开始时间: 23年07月23日 17:22  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following reactions will have the greatest dery,rp b k9cg hf)r/3tiwa) g:)crease in entropy?

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following combinationsftf- xz+ od3tw utz/*: of ΔH and ΔS results in the most spontaneous react-u3tz xf:+ zt*ot/d fwion at 298 K?

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following st7vai0 v x7;-a0b6v/pkh mbqwu atements about entropy is incorrect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the followin5o fk8)y5jqjzt5fma1g compounds are arranged in order of decreasing entropy?

$C$(s)
$H_2O$(l)
$O_2$
$CO_2$(g)
>

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is true for an endothermic red w ld,w.ifo(x6ke- 1zaction that results in an increase in entropzfel do,xdk-w 1w. (i6y?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about the relationshi1q3yzc8nahgb a; hj18p between Gibbs free energy change and the equilibrium constant is c8ghqnja 8a h1byz;1c3orrect?

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following factors affect the entropy of a system containing gases?6atjbh.h 7r*q3fwh ,b t 7,6f3rjhawh*qh. bb
I. The temperature of the system
II. The states of the system
III. The pressure of the system

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8#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Gibbs free energy change can be used to determin /, fu7qnwbx c.kbake)p)3bh*,m8i b ve the spontaneity of a reaction,i pk*m ckbwbb,eh7nv)f )u/qb83.a x.
1.1.Define Gibbs free energy change of formation.
1.2.Define spontaneous reaction.

2.1.State a correctly balanced equation that represents the complete combustion of butane.

2.2.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the Gibbs free energy change of this reaction.
ΔG$_{reaction}$=-  kJ mol$^{-1}$
2.3.State, with a reason, whether this reaction is spontaneous or not.

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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9#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Methanol is produced by reacting carbon monoxide and hydrogen accordinze yyfx7 -/re0-sp a a,nl ja*qq5cu0)g to the following reaction:n--5ycaj0fleapyu rea*0 7)szq,q x /
$CO(g)$+2$H_2(g)$ → $CH_3OH$(g)
$CO(g)$+2$H_2(g)$ ← $CH_3OH$(g)
1.Deduce the equilibrium constant expression for the formation of methanol.
At 500$^{\circ}C$ ,a 750cm$^3$ sealed flask is found to contain 0.923 mol of CH_3OH, 0.352mol of CO and 0.124 mol of $H_2$.
2.1.Calculate the value of K$_c$ at 500 $^{\circ}C$. K$_c$= 
2.2.Using sections 1 and 2 of the data booklet, calculate ΔG$^θ$ at 500 $^{\circ}C$.
T=  K;ΔG$^θ$=-  kJ mol$^{-1}$

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Ethanol can be produced throughg*g; 5r: v2//8wn t,winu7vv smdzxvz ) wbe8z the fermentation of glucose:
$C_6H_12O_6$(aq)→2$C_2H_5OH$(l)+2$CO_2$(g)
1.1.Predict whether the entropy change for this reaction is positive or negative. Explain your reasoning.
1.2.The absolute entropy for glucose is +209.2 J K$^{-1}$ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change for this reaction.
ΔS$_{reaction}$=+  JK$^{-1}$ mol$^{-1}$

2.The enthalpy of formation of glucose is -1273.3kJ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the enthalpy change for this reaction.
ΔH$_{reaction}$=-  kJ mol$^{-1}$

3.Using your answers to (a)(ii) and (b), calculate the Gibbs free energy change at 298K.
ΔG=-  kJ mol$^{-1}$
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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11#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Dry ice, solid $CO_2$,is commonly used as a cooling or freezing agent in the medical and food industries.
1.Write an equation representing the sublimation of $CO_2$.
2.The enthalpy of sublimation for $CO_2$ is +26.1kJ mol$^{-1}$ and the absolute entropy of $CO_2$ in the solid state is 51.1 J K$^{-1}$ mol$^{-1}$.
2.1.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change associated with the sublimation of $CO_2$.
ΔS$_{reaction}$=+  J K$^{-1}$ mol$^{-1}$
2.2.Using your answer to (bi), calculate the Gibbs free energy change for the sublimation of $CO_2$ at K.
ΔG=-  kJ mol$^{-1}$

3.Calculate the minimum temperature at which $CO_2$ sublimates.
T>  K

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  How does Gibbs free e 1.nwk: z g6shi 5xzqc((j6u4i crh3gvnergy relate to chemical equilibrium?

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13#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reactioy+6qjbu:llr 5gu5t: rn:
$C_2H_4$(g)+$H_2$(g)→$C_2H_6$(g)
ΔH is -136kJ mol$^{-1}$
ΔS is -121jk$^{-1}$ mol$^{-1}$
ΔG at 298K is -99.9kJ mol$^{-1}$
1.1.Explain why the enthalpy of formation of $H_2$ is 0 kJ mol$^{-1}$.
1.2.Explain why the entropy change for this reaction is negative.

2.Explain how a reaction can be spontaneous with a negative entropy change.

3.Calculate the temperature at which this reaction is no longer spontaneous.
T=  K

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The following graph shows the Gibbs free energy against the extent of remybrx8w t( eptcw2q340: uu 1g anyhk44z if07action for a reversible1x( 08ci3em z uqthwrufya0tnk42:ywg4 47b p reaction.
At what point is the reaction at equilibrium?




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