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习题练习:What Drives Chemical Reactions D.4 Entropy and Spontaneity



 作者: admin   总分: 14分  得分: _____________

答题人: 匿名未登录  开始时间: 23年07月23日 17:22  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following reactions will have the greatest de t:eb*ol j-/rmcrease in entropy?

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following combinations of ΔH and ΔS results in the most spoq*ulnv+( 7 4mmr8n bnmqdp 8;gntaneous reactionbr mvlm8m n7n+up8q;4dq*(gn at 298 K?

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following statements wpjt3 y(2gbg bi9w(+ihqn6xzt7g,i2 about entropy is incorrect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following compoora b3/9ff sc8unds are arranged in order of decreasing entropy?

$C$(s)
$H_2O$(l)
$O_2$
$CO_2$(g)
>

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is true for an endothermic rho7v7oogoa)b fcp qf94+5ph h3 b57kteaction that results in an increase in enp75kv7cpt 7o) oqb+3hb4 haffh 59oogtropy?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about the relationship between Gibbs free energy change and fbzwpgc++a1 v1*e -q +qlc-y)dd86e) nxl uzx the equilibriu+gl*qne-wb- y+u1c zd+ 6 )1azxvx d)8elqpcfm constant is correct?

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following factors affect the entropy of a system c-cxc/ ig60ulfd9r2t a ontaining gases? 0g xl-/c uri9cdtf26a
I. The temperature of the system
II. The states of the system
III. The pressure of the system

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8#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Gibbs free energy change can be used to determine the spontaneity of a qfev(-wghz.v3 0 ;fup reaction; zhwg- uf v3(fpeq0.v.
1.1.Define Gibbs free energy change of formation.
1.2.Define spontaneous reaction.

2.1.State a correctly balanced equation that represents the complete combustion of butane.

2.2.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the Gibbs free energy change of this reaction.
ΔG$_{reaction}$=-  kJ mol$^{-1}$
2.3.State, with a reason, whether this reaction is spontaneous or not.

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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9#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Methanol is produced(a5 gi oao)2hh ky0fcm2z47ow by reacting carbon monoxide and hydrogen according to the following reaction:4wych20 )z(a foo a2hm i5go7k
$CO(g)$+2$H_2(g)$ → $CH_3OH$(g)
$CO(g)$+2$H_2(g)$ ← $CH_3OH$(g)
1.Deduce the equilibrium constant expression for the formation of methanol.
At 500$^{\circ}C$ ,a 750cm$^3$ sealed flask is found to contain 0.923 mol of CH_3OH, 0.352mol of CO and 0.124 mol of $H_2$.
2.1.Calculate the value of K$_c$ at 500 $^{\circ}C$. K$_c$=  
2.2.Using sections 1 and 2 of the data booklet, calculate ΔG$^θ$ at 500 $^{\circ}C$.
T=  K;ΔG$^θ$=-  kJ mol$^{-1}$

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Ethanol can be produced le6n+moq.f*8 3 cnl8yo1puxwh +x bf,through the fermentation of glucose:
$C_6H_12O_6$(aq)→2$C_2H_5OH$(l)+2$CO_2$(g)
1.1.Predict whether the entropy change for this reaction is positive or negative. Explain your reasoning.
1.2.The absolute entropy for glucose is +209.2 J K$^{-1}$ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change for this reaction.
ΔS$_{reaction}$=+  JK$^{-1}$ mol$^{-1}$

2.The enthalpy of formation of glucose is -1273.3kJ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the enthalpy change for this reaction.
ΔH$_{reaction}$=-  kJ mol$^{-1}$

3.Using your answers to (a)(ii) and (b), calculate the Gibbs free energy change at 298K.
ΔG=-  kJ mol$^{-1}$
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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11#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Dry ice, solid $CO_2$,is commonly used as a cooling or freezing agent in the medical and food industries.
1.Write an equation representing the sublimation of $CO_2$.
2.The enthalpy of sublimation for $CO_2$ is +26.1kJ mol$^{-1}$ and the absolute entropy of $CO_2$ in the solid state is 51.1 J K$^{-1}$ mol$^{-1}$.
2.1.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change associated with the sublimation of $CO_2$.
ΔS$_{reaction}$=+  J K$^{-1}$ mol$^{-1}$
2.2.Using your answer to (bi), calculate the Gibbs free energy change for the sublimation of $CO_2$ at K.
ΔG=-  kJ mol$^{-1}$

3.Calculate the minimum temperature at which $CO_2$ sublimates.
T>  K

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  How does Gibbs free energy relate to chemicalv1+j bq)zbtp*q ns35i equilibrium?

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13#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the followingtb ga2-t8 zzv* reaction:
$C_2H_4$(g)+$H_2$(g)→$C_2H_6$(g)
ΔH is -136kJ mol$^{-1}$
ΔS is -121jk$^{-1}$ mol$^{-1}$
ΔG at 298K is -99.9kJ mol$^{-1}$
1.1.Explain why the enthalpy of formation of $H_2$ is 0 kJ mol$^{-1}$.
1.2.Explain why the entropy change for this reaction is negative.

2.Explain how a reaction can be spontaneous with a negative entropy change.

3.Calculate the temperature at which this reaction is no longer spontaneous.
T=  K

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The following graph 8u(5.gqw 1d*crd;djwkz xk* pshows the Gibbs free energy against the extent of reaction for a revjg c*dz(d1qw kw.8x;*ku rd 5persible reaction.
At what point is the reaction at equilibrium?




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