A voltmeter reading is recorded asuz0)kv y:a6xr fxox2af 4f79v 100.0 V +/- 2%. Which of the following could bva u9fyr0o f az6x7f:xv4)x2k e the actual value?

I.98.0V
II.97.2V
III.101.3V

  A student recorded the volume of a gas as 0.040hntg tyofoo;q):q 5 ;,56m$^3$. How many significant figures does the recorded value have?

  Which of the below features must be included in a sketcp9+neasx; 2qr hed graph?

I.Labelled axes
II.Scaled axes
III.Plotted points

  For the graph below, state) c-a)c;hnopef/aezp, 3q4gn the appropriate units for the y-intercept.

  Which statement best describes the relationshi89ho hfmgbo,3 /bnu4 id20srxp between x and y on the graph beloh2ohomud/8br0, xnfs gib3 94w?

For a first order reacsz1mq0fqr 4tu i-,: zstion, the relationship between rate and the concentration of a reactant, [A], can be shqz: z,ssr0q4fm uti 1-own using the following equation: rate =k[A].
The data below gives the rate information for the first order reaction that proceeds in the thermal decomposition of reactant A.



1.On the axes above, draw a graph based on the provided data.
2.The effect of time on the concentration of reactant B for a zero-order reaction was plotted on the graph below.

(i)Draw a line of best fit on the graph above.
2.Describe the relationship between time and concentration.

  Which of the below gives the correct units for the gradibhsa);1 dy5 7(sr; u dnhqem3nent of this line?

  A student is measuring the temperature change of an (,8mes,de9zq tgfm7 f endothermic reaction.
Calculate the temperature change and identify the corresponding error.



Temperature decrease:  $^{\circ}C$$\pm$  $^{\circ}C$

  The relationship between pressure and i1prwc ,p u u4*,mcoq/temperature of a known volume and amount of gas can be described usicw qru4c*pimu1o/, p,ng Gay-Lussac’s law which states that pressure is directly proportional to temperature.P∝T
Where P is pressure in Pa, and T is temperature in K.




1.On the axes above, sketch the graph of P∝T.

2.State two features that would need to be added to your sketched graph to turn it into a drawn graph.

3.The proportionality can be shown in an equation by incorporating a constant, k. The equation becomes P=kT, and follows the format of the equation of a straight line.

3.1.State the feature of a straight line that k represents in this context.
The feature is   .
3.2.Deduce the y-intercept of the straight line.
it is   (Pa).

  What is the value for the gradientt)gs3 ;sfcu .w of the graph below with the correct units?

  A given mass of magnesium was added to 500cm$^3$ of aqueous hydrochloric acid in a Styrofoam cup to form magnesium chloride. The temperature at the start was 18$^{\circ}C$ and and after the magnesium had dissolved, the temperature rose to 20$^{\circ}C$.
1.State a balanced chemical equation for this reaction.
2.Given that the change in enthalpy,ΔH is 0.185kJ and the specific heat capacity of water is 4.18J g$^{-1}$K$^{-1}$,calculate the mass of magnesium added to the hydrochloric acid.
m=  g
3.Determine the systematic errors caused by the use of styrofoam cups.

Solid sodium carbonate reacts with excess nitric acid of 0.1 mol dm$^{-1}$ as shown in the equation below:
$Na_2CO_3$(s)+2$HNO_3$(aq) → $H_2O$(l) +$CO_2$(g)+2$NaNO_3$(aq)
1.State a method to measure the rate of reaction other than measuring the volume of gas collected.
2.1.Sketch a graph to show the volume of gas produced over time.
2.2.Explain the shape of your graph using the collision theory.


3.On the same graph as in part(bi), sketch another line to show the volume of gas collected over time at a concentration of 0.05 molcdm$^{-3}$ of nitric acid and label it as X.


4.Suggest and describe a factor other than the concentration that can affect the rate of the above reaction.

  Which statement best describes the relationship between the rate l792 dy lrh/z.g0 bhzdand H$^+$ oncentration, in a graph with the equation: rate =k[H$^+$]$^2$?

  In a first order reaction, the concentration [A] of t-i*q/ifu;nvb :. befa given reactant can be determined at time t, according to the equation below, itiq.- *ff; n/bevu b:where [A]$_o$ is the initial concentration of A and k is the rate constant.
ln[A]=-kt+ln[A]$_o$

  The enthalpy of neutrac,yz) i2ndauh7wr6 6 ii3vvf 6lization for the reaction between sulfuric acid and potassium hydroxide can be determ ifwia6i3 ,uv y6cdzn)h 672vrined experimentally.
$H_2SO_4$(aq)+2KOH(aq)→$K_2SO_4$(aq)+2$H_2O$(l)
A student recorded the temperature of 20.0cm$^3$ of 0.500 mold m$^{-3}$
sulfuric acid every minute. At four minutes,25.0cm$^3$KOH(aq) is added to the solution, stirred immediately, and temperature recorded for another four minutes. The results are represented in the graph below.

1.Calculate the lowest concentration of aqueous KOH that must be used to ensure it is in excess.
C$_{KOH}$=  mold m$^{-3}$
2.Use the graph above to estimate a value for the maximum temperature change,ΔT.
ΔT=  $^{\circ}$
3.State one assumption you made in part (b).
4.Identify the anomalous result and suggest a possible type and source of error.
5.In another experiment with the same reactants, the student measured the initial and final temperatures and presented their results below:
Initial Temperature ($^{\circ}$C $\pm$$^{\circ}$C) 24.8 25.1 24.9
Final Temperature($^{\circ}$C $\pm$$^{\circ}$C) 26.4 26.6 26.4
1.Calculate the average change in temperature (ΔT)giving its percentage uncertainty.
Average=  $^{\circ}$C; Absolute uncertainty=$\pm$  $^{\circ}$C; Percentage uncertainty=  %
2.Use sections 1 and 2 of the data booklet to calculate the energy released and its uncertainty. You may assume that the only source of uncertainty is from the temperature change.
Energy released (q)=  J;Uncertainty=$\pm$  J

  Determine the type of variable and correct axis for ΔH in a graph to show hom.0b x*(wfki bw ΔH is affected by t 0b.mwfi (*kxbhe length of the carbon chain.

  The initial mass of a mortar containing a solid was recorded to be 10, k1qns,b o9am9.34 g. The mortar was heated, and the final mass was recorded to be 81.92 g. What value should be o 1sa m,bn9,kqrecorded for the mass lost in grams?

  The half-life of a sk0ijhy6c , odr dzw-;7econd order reaction can be expressed according to the equatik,d6ihozdc y r-0 7j;won below.
t$^{$\frac{1}{2}$}$=$\frac{1}{k[A]_0}$
Where t$^{\frac{1}{2}}$ =half-life,[$[A]_0$]= initial concentration of reactant A,and k is a constant.
Which two variables plotted against each other would produce a straight line?
I.t$^{\frac{1}{2}}$ VS $\frac{1}{k}$
II.t$^{\frac{1}{2}}$ VS $[A]_0$
III.t$^{$\frac{1}{2}$}$ VS $\frac{1}{[A]_0}$

  A piece of sodium metal has a mass of 13.02 g and a38krkjcdf3 ns tp(8r3 l;b9ri volume of 13.4 cm$^3$. What is the most precise density that can be reported?

1.State the complete balanced equation for the reaction -6 zo) 4tkl1 +/vaeb 4vvjc .ef.4cn(b zyfaimbetween sulphuric acid ab(vefv)m6cb 1z yc/kla444a.nzf -j .+oi tvend copper (II) oxide.
2.State the complete balanced equation for the reaction between ethanoic acid and potassium carbonate.
3.Outline two ways to monitor the rate of reaction for reaction (b) above.

  The relationship between energy, E, and wavryj f d i23r7xa2l1tfs86k-yy cq(5qvelength, λ, is shown according to the equation belowsdcaf8yfl x7q(qvrt r53y 26yi-k j2 1.
E=$\frac{hc}{λ}$

Which of the below statements are correct for the graph below representing E=$\frac{hc}{λ}$?
I.Energy and wavelength are directly proportional
II.The units for the gradient are J m$^{-1}$
III.The y-intercept has the units J

  The feasibility of a reaction proceeding spontaneously can be prer srdthu12 9-2i7scl mdicted using the following eqr mt1 s9uh7ic-2 2srlduation:
ΔG=−TΔS+ΔH.
Where ΔG is the change in Gibb’s free energy, ΔS is the change in entropy, and ΔH is the change in enthalpy.




1.When ΔG<0, a reaction can be described as spontaneous. Use the graph above to deduce the lowest temperature at Read graph at which the reaction becomes spontaneous.
Read graph at ΔG=0,  K.
2.Calculate the gradient of the line and state its units.
3.Use your answer to part (b) to deduce the value and correct units for ΔS.
ΔS=  kJ mol$^{-1}$K$^{-1}$
4.Use the graph to determine the value for ΔG when the temperature is raised to 675K.
5.Calculate a value for y-intercept and state the correct units.
Substitution of (x,y) values and slope into equation with correct evaluation=  .(c=)

  The potential of a cell under non-standar6lzr(5j d 0/1vvyxtd od conditions can be calculated using the Nern6vr ydt0d1j ov5zx( /lst equation:
E=E$^θ$=$\frac{RT}{nF}$ln$_Q$
For the graph below, which components of the equation represent the gradient and the y-intercept?

  The relationship between the concenx damvtpdff,- g85z9- tration of a reactant, A, and the time, for a second-order reaction can be ex,a m8gdfx5pdv9t--fz pressed using the equation below:
$\frac{1}{[A]}$=kt+$\frac{1}{[A]_o}$
Where [A] is the concentration of reactant A,$[A]_o$,is the initial concentration of reactant A,t is the time in seconds, and k is a constant.

1.Calculate the gradient of the line and state the correct units.
2.Use the graph to determine $[A]_o$ (also known as the initial concentration of A)
$[A]_o$=  mol dm$^{-3}$
3.Determine the time at which the concentration of A is equal to an eighth of its initial concentration.
(If you were unable to complete parts (a), and (b), you may use k=0.02, and $A_o$=42)
[A]=  mold m$^{-3}$;Substitute and rearrange:  seconds

  Which of the below gives the correct averagv fk8nt3k7ru cxp2*u (e titre with its uncertainty?
Initial volume $\pm $0.05 c m$^{3}$ 0.00 23.15 0.00
Final volume $\pm $0.05 c m$^{3}$ 23.15 46.25 23.20

  The length of a thread was being measured using a 50 cm wooden ru+)gw4p1e iocs+vaud7 ler with a 1 mm increment. The reading for the beginnind+7gp1o s uai)ec4v +wg of the thread was 12.6 cm while the reading for the end of the thread was 45.3 cm. Which of the following is the largest possible length of the thread?

  The ideal gas equation allows pressure to ;v+cd7 zoltl 7be calculated according to the equatiovl77lc to+;dz n,
P=$\frac{nRT}{V}$.
This allows a straight line to be drawn for the effect of $\frac{1}{V}$ on P.

For the sketched graph above, which components of the equation P=$\frac{nRT}{V}$,relate to the gradient and
y-intercept of the straight line?

  A student recorded the mass of solid NaCl as 1200 g. Which of the folnzid7+ v ;*b virfp,q;lowing is correct about the number of significant figures rpnz7*; rq ,v +dvbiif;ecorded?

  2.00 ± 0.02 g $NaClO_3$ were dissolved in 2.0 ± 0.5 dm$^3$ distilled water.

Which row gives the correct concentration in gd m$^{-3}$ and relative uncertainty?

  A student is measuring the density of a solution. He recorded izj5lj;a m 2j)the data in the following tabl;jlmj 2zi )aj5e.

1.Write the expression of the average density of the solution in a fraction form (make sure to include the absolute uncertainties for each physical quantity).
2.Calculate its corresponding uncertainty. Show your work clearly.
   $\pm$    %