A voltmeter reading is recorded as 10t sae061nszvse3x)q+0.0 V +/- 2%. Which of the following could be the actu0q)svs x+ 6 sz31teaneal value?

I.98.0V
II.97.2V
III.101.3V

  A student recorded the volume of a gas as 0.040 6x5 irx/ipf3q56m$^3$. How many significant figures does the recorded value have?

  Which of the below features must be d 9l2pmljmrw(.-k+g9 rlbc (i included in a sketched graph?

I.Labelled axes
II.Scaled axes
III.Plotted points

  For the graph below, state tm ntlw()el.: w2*ehzb zte9k 3he appropriate units for the y-intercept.

  Which statement best describes the relationship bet3t g-271 xxt;lk- 9vlpgrvklvween x and y on the graph below? -g9v t;-tvk1l lv3xglp7x 2kr

For a first order reaction, t e*:3 i7s3khbwxbqdte+ j) ;rqhe relationship between rate and the concentration of a reactant, [A], can be shown using the following equation: rate = dqhe ixbw*stj; rek)bq3:73+k[A].
The data below gives the rate information for the first order reaction that proceeds in the thermal decomposition of reactant A.



1.On the axes above, draw a graph based on the provided data.
2.The effect of time on the concentration of reactant B for a zero-order reaction was plotted on the graph below.

(i)Draw a line of best fit on the graph above.
2.Describe the relationship between time and concentration.

  Which of the below gives1fy7 q:(9ysxn ufin,g the correct units for the gradient of this line?

  A student is measuring the temperature change of an endfao4sl 3vwdq(y. zfd8 tm4 /x(othermic reaction.
Calculate the temperature change and identify the corresponding error.



Temperature decrease:  $^{\circ}C$$\pm$  $^{\circ}C$

  The relationship between pressure and temperature of a known volume and ar9in9e7cduftq/ ;j,v h6bz7 bmount of gas can be described usingd6qz7tbi79jf9 cn uve;,h rb/ Gay-Lussac’s law which states that pressure is directly proportional to temperature.P∝T
Where P is pressure in Pa, and T is temperature in K.




1.On the axes above, sketch the graph of P∝T.

2.State two features that would need to be added to your sketched graph to turn it into a drawn graph.

3.The proportionality can be shown in an equation by incorporating a constant, k. The equation becomes P=kT, and follows the format of the equation of a straight line.

3.1.State the feature of a straight line that k represents in this context.
The feature is   .
3.2.Deduce the y-intercept of the straight line.
it is   (Pa).

  What is the value for the gradient of the graph below with the correct unp b r1e(zzuk68its?

  A given mass of magnesium was added to 500cm$^3$ of aqueous hydrochloric acid in a Styrofoam cup to form magnesium chloride. The temperature at the start was 18$^{\circ}C$ and and after the magnesium had dissolved, the temperature rose to 20$^{\circ}C$.
1.State a balanced chemical equation for this reaction.
2.Given that the change in enthalpy,ΔH is 0.185kJ and the specific heat capacity of water is 4.18J g$^{-1}$K$^{-1}$,calculate the mass of magnesium added to the hydrochloric acid.
m=  g
3.Determine the systematic errors caused by the use of styrofoam cups.

Solid sodium carbonate reacts with excess nitric acid of 0.1 mol dm$^{-1}$ as shown in the equation below:
$Na_2CO_3$(s)+2$HNO_3$(aq) → $H_2O$(l) +$CO_2$(g)+2$NaNO_3$(aq)
1.State a method to measure the rate of reaction other than measuring the volume of gas collected.
2.1.Sketch a graph to show the volume of gas produced over time.
2.2.Explain the shape of your graph using the collision theory.


3.On the same graph as in part(bi), sketch another line to show the volume of gas collected over time at a concentration of 0.05 molcdm$^{-3}$ of nitric acid and label it as X.


4.Suggest and describe a factor other than the concentration that can affect the rate of the above reaction.

  Which statement best myv u p0co:/;v t; ,+uwxa6wqedescribes the relationship between the rate and H$^+$ oncentration, in a graph with the equation: rate =k[H$^+$]$^2$?

  In a first order reaction, the concentration [A] of a given reactant ca ;wv mra);0 8hgw )wn9o (xh,5aocdxcxn be determined at time t, according to the equati5hx;a9wocxm) hww o8 );a0v,n( gdcx ron below, where [A]$_o$ is the initial concentration of A and k is the rate constant.
ln[A]=-kt+ln[A]$_o$

  The enthalpy of neutralization for tkm, x *nwn*3omhe reaction between sulfuric acid and potassium hydroxide can bm xn3* mnko,w*e determined experimentally.
$H_2SO_4$(aq)+2KOH(aq)→$K_2SO_4$(aq)+2$H_2O$(l)
A student recorded the temperature of 20.0cm$^3$ of 0.500 mold m$^{-3}$
sulfuric acid every minute. At four minutes,25.0cm$^3$KOH(aq) is added to the solution, stirred immediately, and temperature recorded for another four minutes. The results are represented in the graph below.

1.Calculate the lowest concentration of aqueous KOH that must be used to ensure it is in excess.
C$_{KOH}$=  mold m$^{-3}$
2.Use the graph above to estimate a value for the maximum temperature change,ΔT.
ΔT=  $^{\circ}$
3.State one assumption you made in part (b).
4.Identify the anomalous result and suggest a possible type and source of error.
5.In another experiment with the same reactants, the student measured the initial and final temperatures and presented their results below:
Initial Temperature ($^{\circ}$C $\pm$$^{\circ}$C) 24.8 25.1 24.9
Final Temperature($^{\circ}$C $\pm$$^{\circ}$C) 26.4 26.6 26.4
1.Calculate the average change in temperature (ΔT)giving its percentage uncertainty.
Average=  $^{\circ}$C; Absolute uncertainty=$\pm$  $^{\circ}$C; Percentage uncertainty=  %
2.Use sections 1 and 2 of the data booklet to calculate the energy released and its uncertainty. You may assume that the only source of uncertainty is from the temperature change.
Energy released (q)=  J;Uncertainty=$\pm$  J

  Determine the type of variable and correct axis forvv 8qjf(oj4 .w+)a-xeixx j wty462ww ΔH in a graph to show how ΔH is affected by the length of the ca(8i4e f-v) xx j tayjjw24wq6v+w.oxwrbon chain.

  The initial mass of a mortar containing a solid was recorded to-o2z g7qr/,x zqga+o9is km(4fl3chn be 109.34 g. The mortar was heat2cshqaqk9mxz/-lgr , 3g z fn o+(io74ed, and the final mass was recorded to be 81.92 g. What value should be recorded for the mass lost in grams?

  The half-life of a second order reaction can be expresi9 cq o24c)hr u+t6duvsed according to the equation be6 c 9uu2q4vt r)oh+idclow.
t$^{$\frac{1}{2}$}$=$\frac{1}{k[A]_0}$
Where t$^{\frac{1}{2}}$ =half-life,[$[A]_0$]= initial concentration of reactant A,and k is a constant.
Which two variables plotted against each other would produce a straight line?
I.t$^{\frac{1}{2}}$ VS $\frac{1}{k}$
II.t$^{\frac{1}{2}}$ VS $[A]_0$
III.t$^{$\frac{1}{2}$}$ VS $\frac{1}{[A]_0}$

  A piece of sodium metal has a mar i 9n/yyxtihek+i+;5 ss of 13.02 g and a volume of 13.4 cm$^3$. What is the most precise density that can be reported?

1.State the complete balanced equation for the reaction be2lcldatr4i415 9 gf xbtween sulphuric acid and copper (II) oxide. 2d15 ialcg4tf9 rl4 xb
2.State the complete balanced equation for the reaction between ethanoic acid and potassium carbonate.
3.Outline two ways to monitor the rate of reaction for reaction (b) above.

  The relationship between energy, E, and wavd6 m3sc,2xx2drzv 8haelength, λ, is shown according to the eqdsd2hxvm2,6x cz ar38 uation below.
E=$\frac{hc}{λ}$

Which of the below statements are correct for the graph below representing E=$\frac{hc}{λ}$?
I.Energy and wavelength are directly proportional
II.The units for the gradient are J m$^{-1}$
III.The y-intercept has the units J

  The feasibility of a reaction proceeding spontaneously can be 1s66pji4sg s3ma(*,wo9a* sbtez quipredicted using the following equatioi4qs*ipjusastb *6z9ow1 ,(s 3 6aegmn:
ΔG=−TΔS+ΔH.
Where ΔG is the change in Gibb’s free energy, ΔS is the change in entropy, and ΔH is the change in enthalpy.




1.When ΔG<0, a reaction can be described as spontaneous. Use the graph above to deduce the lowest temperature at Read graph at which the reaction becomes spontaneous.
Read graph at ΔG=0,  K.
2.Calculate the gradient of the line and state its units.
3.Use your answer to part (b) to deduce the value and correct units for ΔS.
ΔS=  kJ mol$^{-1}$K$^{-1}$
4.Use the graph to determine the value for ΔG when the temperature is raised to 675K.
5.Calculate a value for y-intercept and state the correct units.
Substitution of (x,y) values and slope into equation with correct evaluation=  .(c=)

  The potential of a cell under non-stawh87 6bokzh-y ndard conditions can be calculated using the Nernhk8 -76wo hybzst equation:
E=E$^θ$=$\frac{RT}{nF}$ln$_Q$
For the graph below, which components of the equation represent the gradient and the y-intercept?

  The relationship between the concentration of a reactant, A, and the time, f3ef k/d7: abjror a secor/d7a kbef j:3nd-order reaction can be expressed using the equation below:
$\frac{1}{[A]}$=kt+$\frac{1}{[A]_o}$
Where [A] is the concentration of reactant A,$[A]_o$,is the initial concentration of reactant A,t is the time in seconds, and k is a constant.

1.Calculate the gradient of the line and state the correct units.
2.Use the graph to determine $[A]_o$ (also known as the initial concentration of A)
$[A]_o$=  mol dm$^{-3}$
3.Determine the time at which the concentration of A is equal to an eighth of its initial concentration.
(If you were unable to complete parts (a), and (b), you may use k=0.02, and $A_o$=42)
[A]=  mold m$^{-3}$;Substitute and rearrange:  seconds

  Which of the below gives the correct y5pf)-ks8rzz /e q1hpaverage titre with its uncertainty?
Initial volume $\pm $0.05 c m$^{3}$ 0.00 23.15 0.00
Final volume $\pm $0.05 c m$^{3}$ 23.15 46.25 23.20

  The length of a thread was being measukrbf ln*,a2zw(0n7 kf red using a 50 cm wooden ruler with a 1 mm increment. The reading for the beginning of the thread was 12.6 cm while the reading for the end of the thread was 45.3 cm. Whicha(,f lr2 fnb nwk*0k7z of the following is the largest possible length of the thread?

  The ideal gas equation allows pressure to be 0*7 y+e:g fy tc6 yoo67hiuopyq yw9b5calculated according to the equation, 7+pyyq9bt fyoig 570w 6oyeyuh :o6*c
P=$\frac{nRT}{V}$.
This allows a straight line to be drawn for the effect of $\frac{1}{V}$ on P.

For the sketched graph above, which components of the equation P=$\frac{nRT}{V}$,relate to the gradient and
y-intercept of the straight line?

  A student recorded the mass of s-,bymr.h24ynquphq( f) gu) smp9,uaolid NaCl as 1200 g. Which of the following is corr. g4ahbqpr qpu,u)(y2y-9mn ) hu,mfsect about the number of significant figures recorded?

  2.00 ± 0.02 g $NaClO_3$ were dissolved in 2.0 ± 0.5 dm$^3$ distilled water.

Which row gives the correct concentration in gd m$^{-3}$ and relative uncertainty?

  A student is measuring the density of a solution. He recorded the data i3b sb +2* p4/qutz bghop,zud4/dhh -xn the followinp4 *b 4xqudthz,hhps 3o/bub+-/2 dgzg table.

1.Write the expression of the average density of the solution in a fraction form (make sure to include the absolute uncertainties for each physical quantity).
2.Calculate its corresponding uncertainty. Show your work clearly.
   $\pm$    %