A voltmeter reading is recorded as 100.0 V +/- 2%. Which of the following1 .t)ej8z orwc9/ dmkz(e9x mx could be the actual valuj/tzw.e8om x9 9mxre(d)k1c ze?

I.98.0V
II.97.2V
III.101.3V

  A student recorded the volume of a gas as 0.04056mm4 t7o7t)q(x i;glaik$^3$. How many significant figures does the recorded value have?

  Which of the below features u:dwf ,dm42vcmust be included in a sketched graph?

I.Labelled axes
II.Scaled axes
III.Plotted points

  For the graph below, state the appropriat ,gt2hv3 vqg8i1m a7qeoeqt7.e units for the y-intercept.

  Which statement best describes the relationship between x and y on the graph bel81z8z()vpxgdrc (xrv b;s(xk ow? 8v xdg;b xxz(z(s) rcv8kr1p(

For a first order reaction, the rel+t 70cmf 1dg+ st4mpz)lu5 wahationship between rate and the concentration of a reactant, [A], can be shown using the tlw45+ z 7p0+1fsdam)ug mt hcfollowing equation: rate =k[A].
The data below gives the rate information for the first order reaction that proceeds in the thermal decomposition of reactant A.



1.On the axes above, draw a graph based on the provided data.
2.The effect of time on the concentration of reactant B for a zero-order reaction was plotted on the graph below.

(i)Draw a line of best fit on the graph above.
2.Describe the relationship between time and concentration.

  Which of the below gives the 3-nr0 zcyc.ri4q4 ccpcorrect units for the gradient of this line?

  A student is measuring the temperature ch+u z7f:lk e:h2kyoj/ lange of an endothermic reaction.
Calculate the temperature change and identify the corresponding error.



Temperature decrease:  $^{\circ}C$$\pm$  $^{\circ}C$

  The relationship between pressure and temperature of av) -8rwp1* wcf9uq mxt known volume and amount of gas can beq- mcw81tx)vfw 9u *rp described using Gay-Lussac’s law which states that pressure is directly proportional to temperature.P∝T
Where P is pressure in Pa, and T is temperature in K.




1.On the axes above, sketch the graph of P∝T.

2.State two features that would need to be added to your sketched graph to turn it into a drawn graph.

3.The proportionality can be shown in an equation by incorporating a constant, k. The equation becomes P=kT, and follows the format of the equation of a straight line.

3.1.State the feature of a straight line that k represents in this context.
The feature is   .
3.2.Deduce the y-intercept of the straight line.
it is   (Pa).

  What is the value for g;vbarc9,+hhbv3 4hy t j3i -fthe gradient of the graph below with the correct units?

  A given mass of magnesium was added to 500cm$^3$ of aqueous hydrochloric acid in a Styrofoam cup to form magnesium chloride. The temperature at the start was 18$^{\circ}C$ and and after the magnesium had dissolved, the temperature rose to 20$^{\circ}C$.
1.State a balanced chemical equation for this reaction.
2.Given that the change in enthalpy,ΔH is 0.185kJ and the specific heat capacity of water is 4.18J g$^{-1}$K$^{-1}$,calculate the mass of magnesium added to the hydrochloric acid.
m=  g
3.Determine the systematic errors caused by the use of styrofoam cups.

Solid sodium carbonate reacts with excess nitric acid of 0.1 mol dm$^{-1}$ as shown in the equation below:
$Na_2CO_3$(s)+2$HNO_3$(aq) → $H_2O$(l) +$CO_2$(g)+2$NaNO_3$(aq)
1.State a method to measure the rate of reaction other than measuring the volume of gas collected.
2.1.Sketch a graph to show the volume of gas produced over time.
2.2.Explain the shape of your graph using the collision theory.


3.On the same graph as in part(bi), sketch another line to show the volume of gas collected over time at a concentration of 0.05 molcdm$^{-3}$ of nitric acid and label it as X.


4.Suggest and describe a factor other than the concentration that can affect the rate of the above reaction.

  Which statement best describes the relation43 dkfr(0tb(t m4rhg xship between the rate and H$^+$ oncentration, in a graph with the equation: rate =k[H$^+$]$^2$?

  In a first order reaction, the concentration [A] of a givj*d k3caoy1tn5 z*w5s: pc:iden reactant can be determined at time t,:n 5o1j5czp* wskta:3ddc*iy according to the equation below, where [A]$_o$ is the initial concentration of A and k is the rate constant.
ln[A]=-kt+ln[A]$_o$

  The enthalpy of neutralization for the reaction betwyiij07i y kyw d(sdu4x2h3(2z een sulfuric acid and potassium hydroxide can be determined experime(iz iy2u(yhd kd7432 0wysxjintally.
$H_2SO_4$(aq)+2KOH(aq)→$K_2SO_4$(aq)+2$H_2O$(l)
A student recorded the temperature of 20.0cm$^3$ of 0.500 mold m$^{-3}$
sulfuric acid every minute. At four minutes,25.0cm$^3$KOH(aq) is added to the solution, stirred immediately, and temperature recorded for another four minutes. The results are represented in the graph below.

1.Calculate the lowest concentration of aqueous KOH that must be used to ensure it is in excess.
C$_{KOH}$=  mold m$^{-3}$
2.Use the graph above to estimate a value for the maximum temperature change,ΔT.
ΔT=  $^{\circ}$
3.State one assumption you made in part (b).
4.Identify the anomalous result and suggest a possible type and source of error.
5.In another experiment with the same reactants, the student measured the initial and final temperatures and presented their results below:
Initial Temperature ($^{\circ}$C $\pm$$^{\circ}$C) 24.8 25.1 24.9
Final Temperature($^{\circ}$C $\pm$$^{\circ}$C) 26.4 26.6 26.4
1.Calculate the average change in temperature (ΔT)giving its percentage uncertainty.
Average=  $^{\circ}$C; Absolute uncertainty=$\pm$  $^{\circ}$C; Percentage uncertainty=  %
2.Use sections 1 and 2 of the data booklet to calculate the energy released and its uncertainty. You may assume that the only source of uncertainty is from the temperature change.
Energy released (q)=  J;Uncertainty=$\pm$  J

  Determine the type of variable and correct axis for Δba-qut* iwa5z3e:. 6gga :ezmH in a graph to show how ΔH is affecee 5a 3-g:bi*mzwtazau.:6g qted by the length of the carbon chain.

  The initial mass of a mortar containing a solid was recorded*bl4 xpy /vrh9 to be 109.34 g. The mortar was heated, and the final mass was recorded to be 81.92 g. What value should be recorded for the mass lost in grly/rp 9vhb4x *ams?

  The half-life of a second order reaction can be expressed ayhrv t6b-o+;wx 7 hwbb*rg+-wccording to the equation bew bw +gybwvo;t7xb+rh *r6h--low.
t$^{$\frac{1}{2}$}$=$\frac{1}{k[A]_0}$
Where t$^{\frac{1}{2}}$ =half-life,[$[A]_0$]= initial concentration of reactant A,and k is a constant.
Which two variables plotted against each other would produce a straight line?
I.t$^{\frac{1}{2}}$ VS $\frac{1}{k}$
II.t$^{\frac{1}{2}}$ VS $[A]_0$
III.t$^{$\frac{1}{2}$}$ VS $\frac{1}{[A]_0}$

  A piece of sodium metal has a mass of 13.02 g and a volusv+ m xfk*x3(cz9inf 5mtj lkjb9s854 me of 13.4 cm$^3$. What is the most precise density that can be reported?

1.State the complete balanced equation for the reatm/ 7 ezado0 t00pem-wi)om x)ction between sulphuric acid and copper (II )w)pte/z7mo 0xt0 ed-om0a im) oxide.
2.State the complete balanced equation for the reaction between ethanoic acid and potassium carbonate.
3.Outline two ways to monitor the rate of reaction for reaction (b) above.

  The relationship between energy, E, and wavelength, λ, is shown )2db7kpjyi7m according to the equation beb ymi dp2)kj77low.
E=$\frac{hc}{λ}$

Which of the below statements are correct for the graph below representing E=$\frac{hc}{λ}$?
I.Energy and wavelength are directly proportional
II.The units for the gradient are J m$^{-1}$
III.The y-intercept has the units J

  The feasibility of a reaction proceeding spontaneously can be predict o71. dtaeui jc-zp9 evvx:).eed using the following equatio: v o.. dveacuixpt9- 17jzee)n:
ΔG=−TΔS+ΔH.
Where ΔG is the change in Gibb’s free energy, ΔS is the change in entropy, and ΔH is the change in enthalpy.




1.When ΔG<0, a reaction can be described as spontaneous. Use the graph above to deduce the lowest temperature at Read graph at which the reaction becomes spontaneous.
Read graph at ΔG=0,  K.
2.Calculate the gradient of the line and state its units.
3.Use your answer to part (b) to deduce the value and correct units for ΔS.
ΔS=  kJ mol$^{-1}$K$^{-1}$
4.Use the graph to determine the value for ΔG when the temperature is raised to 675K.
5.Calculate a value for y-intercept and state the correct units.
Substitution of (x,y) values and slope into equation with correct evaluation=  .(c=)

  The potential of a cell under non-standard conw1 .. n lqj x,n h1zn 8,2,ek0wyhvdbpd.9wuhoditions can be calculated using the dx qho.wp unk , ,.91hwy2wn8 01lh ,dnvbj.ezNernst equation:
E=E$^θ$=$\frac{RT}{nF}$ln$_Q$
For the graph below, which components of the equation represent the gradient and the y-intercept?

  The relationship between the concentration of a reactant, A, and the tlk1 2og3wshrq .q*dwx-k2s jf(z2c3vime, for a second-order reaction 3 s 2-.sq1zowrx2w j3v2f h*(gk cqdklcan be expressed using the equation below:
$\frac{1}{[A]}$=kt+$\frac{1}{[A]_o}$
Where [A] is the concentration of reactant A,$[A]_o$,is the initial concentration of reactant A,t is the time in seconds, and k is a constant.

1.Calculate the gradient of the line and state the correct units.
2.Use the graph to determine $[A]_o$ (also known as the initial concentration of A)
$[A]_o$=  mol dm$^{-3}$
3.Determine the time at which the concentration of A is equal to an eighth of its initial concentration.
(If you were unable to complete parts (a), and (b), you may use k=0.02, and $A_o$=42)
[A]=  mold m$^{-3}$;Substitute and rearrange:  seconds

  Which of the below gives the coaa uat3:drcl9tm0 nsuse t/ m86g70 k1rrect average titre with its uncertainty?
Initial volume $\pm $0.05 c m$^{3}$ 0.00 23.15 0.00
Final volume $\pm $0.05 c m$^{3}$ 23.15 46.25 23.20

  The length of a thread was being m vgsz 3jwd y5ud5li.:(*4s ach7w,aareasured using a 50 cm wooden ruler with a 1 mm increment. The reading for the beginning of the thread was 12.6 cm while the reading for the end of the wu 5 haj4c,(dz. sdli3s5:*av7wrgya thread was 45.3 cm. Which of the following is the largest possible length of the thread?

  The ideal gas equation allows pressure to be calculated according to the equatioc8uu1yy 2(;8aqcmk5,pw brq k1cg b1b; 1b1ubqcq 8 yc2,ay b(gckum1 kp58wrn,
P=$\frac{nRT}{V}$.
This allows a straight line to be drawn for the effect of $\frac{1}{V}$ on P.

For the sketched graph above, which components of the equation P=$\frac{nRT}{V}$,relate to the gradient and
y-intercept of the straight line?

  A student recorded the mass of solid NaCl as 1200 g.zy r3g*:dfjf3zf *sl; Which of the following is correct about the number of significant figure ld3f*;r:jgy zf*3fsz s recorded?

  2.00 ± 0.02 g $NaClO_3$ were dissolved in 2.0 ± 0.5 dm$^3$ distilled water.

Which row gives the correct concentration in gd m$^{-3}$ and relative uncertainty?

  A student is measuring the density of a solution. He recorded the data in the 4bz lfxu9k*s)sir8 e(fok*)x8sf( szbl i49erullowing table.

1.Write the expression of the average density of the solution in a fraction form (make sure to include the absolute uncertainties for each physical quantity).
2.Calculate its corresponding uncertainty. Show your work clearly.
   $\pm$    %