An example of a strong a+cmp ezmf*j b/,y*o f: r9bz6zcid solution is nitric acid. Which statement is correct for this solc b/z*emfp+mz9 j bfoy,*r:6zution?

  Which of the following statements f m8opph22v9* v8e xkfu6ednekrndn9g. -5;o concerning acids and bases is not true?

  Which of the following is w5 m sr 9o6rwwff :wxte+,yp03correct?

  Which statement about a strong acid and its conjugate base is correc0 epl.k*u rqk9t?

  Which of the following expjcakl4ig-l9 4ressions for $K_w$ is correct?

  Which combination of acid and base should be reacted to o) kct;xrx agr-:b (o6mbtain a basic salt?

  A reaction produces carbon dioxide gas and a solution of water with a dissolvel+g v)w.hbuu ,)o l9bgd shu+ uwl )vg 9bgbl),o.alt. What could be the reactants?

  Which combination of acid and base will typically havegfk u.62sgz t e(ok5c0 the lowest pH at the equiv 5su 0fzg6 g2.etokck(alence point in a titration?

  In order to prepare a solution oo *2ah.*twg 8)vus jcff $0.1mol\:dm^{-3}$ with the highest pH, substance XX is dissolved in water. Substance X is

  Water dissociates partially and the value of the ioniwkwd;r mgn3i p.w+xi2;(x,ioc+4 u y kc product constant of waterniir u ;xy,opmiw4 (dk+3cwg +2kx;.w at $25^{\circ}$ is $1.00\times10^{-14}$.
1.State an equation for the dissociation of water.
2.Calculate the pH of a $0.0100mol\:dm^{-3}$ of lithium hydroxide at 298K.  
3.Explain whether a $0.0100mol\:dm^{-3}$ solution of calcium hydroxide will have a higher or lower pH than a $0.0100mol\:dm^{-3}$ solution of lithium hydroxide at the same temperature.  $mol\:dm^{-3}$

  When wine is exposed to air, the ethanol is slowly con4)q ybx5f kwz7;q x+ox).pv wu0ni6eeverted to ethanoic acid. The4xbfv ; qok. yp6qx e+z7n)ww5e)0 xui \ce{pH}pH of a bottle of wine changes from 6.5 to 4.5. The concentration of $[H]^+$ is?

  A molecule of HBr reacts with water to produce tk;:crs5i-ag 8d v;um/ nrog ,ehe charged molecule X. What is the Lewis ,;g/asn di8: om-;ger kcu5 vrstructure of molecule X?

  Alkali solutions canm2fwiwh 4fb be .,vp43 be made by dissolving a basic substance in water.
1.Determine the concentration of a solution of NaOH made by carefully dissolving 5.00 g of NaOH in sufficient distilled water to make $250.0cm^3$ total solution in a volumetric flask.  $mol\:dm^{-3}$
2.An indicator was added to the solution made in (a), and it turned red. Using section 22 (Section 18- 2025 syllabus) in the Data booklet, state a possible indicator used.
3.The temperature of a $50.0cm^3$ sample of the solution containing the indicator from (b) was found to be $22.0^{\circ}C$. Suggest with a reason, two possible observations if a slightly larger quantity of HCl was added and stirred.
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers for the 2025 syllabus.

  An aqueous solution of nitric aci;95 bs8 gsj g4i,rrtdjg+cs )ud $HNO_3$ has a pH of 4. How many moles of this acid are found in $1 dm^3$ of the solution?

  Which one of the following statements about acidsio3 ct vnzffo5b/:go;9m7 jjd*p2 k; v is/are true?
|. Acids will neutralize bases to form salts
||. Acids produce solutions with pH greater than 7
|||.Acids ionize to form $H^+$ ions when dissolved in water

  What statements about indicators are correctim3f9vv h kn6, gavg+(?
|.Indicators are typically weak acids or weak bases
||.Indicators are different colours in acidic and alkaline conditions
|||.The midpoint of the colour change of an indicator occurs when [$HIn$] = [$In^-$]

  A solution of $1.0\:mol\:dm^{-3}$ HCl is diluted to $0.1\:mol\:dm^{-3}$. Which statement is correct?

  Which expression represents ;e mpqo 61b4ds$K_a$ for $CH_3COOH$?

  Given the following indicators and their behaviours, what will be the cor edoild i1+;gpoth/cf( j82l4rect colours of a solution of 1.0 M KOH d1gf eclj8tpi/24(l+h oido; tested with each indicator?

Indicator	pH range	Colour change (Acid- alkali)
Methyl orange	3.1- 4.4	Red – Orange
Bromocresol green	3.8 - 5.4	Yellow - Blue
Phenolphthalein	8.3 - 10.0	Colourless - Pink

  What is the order of increas p2ebbq;xb01q+q*8mazpw xw9z mmo3 :ing acid strength based on the $pK_a$ values below?

Acid	$pK_a$
$CCI_3COOH$	0.66
$HCOOH$	3.75
$C_6H_5OH$	9.99
$CH_3OH$	15.5

  The structure of the hydrogen phosphate ion is shown. 7d w 17z,f5fu-* k+mhnjemg6 dy1mkhs


How many $H^+$ ions can react with one hydrogen phosphate ion?^+ions can react with one hydrogen phosphate ion?

  Place the following lf(7,u 7y)ybpk1i tmn$1.0\,mol\:dm^{-3}$ solutions in order of increasing pH:
$NaOH,Na_2CO_3,NaCl$

  Which of the following reactions is not a neutralization reactec3 jd0qhh9mnh:vx .*0.c nbfion?

One example of an important buffer systesed 6y-v,ia pl3h 6 mz0m+g)nom is the $H_2CO_3/HCO_3^-$ buffer in our blood.
1. 1.Define buffer solution.
2.Using relevant equations, describe how the $H_2CO_3/HCO_3^-$ buffer works.
A student has solutions of $0.5\,mol\,dm^{-3}$ $NaOH,HCl,H_2CO_3andNaHCO_3$.
2.State two ways the $H_2CO_3/HCO_3^-$buffer can be made from these solutions.

  The reversible reacti: y 2 kpv0c6cze(hwc +kqs0qhmd35j;pon between $NH_3$ and $H_2SO_4$ is:
$NH_3 + H_2SO_4 \rightleftharpoons NH^+_4 + HSO_4^-$
Which compounds act as bases in the forward and backward reactions?

  What is the pH of a bpj1g ,fuk/y3z+c2 bb$0.001\,mol\,dm^{-3}$ aqueous solution of KOH at 298K given that it ionizes completely?

Consider the following reaction: x m.qb6r0o8xq
$H_2SO_4(aq) + NH_3(aq) \rightleftharpoons HSO_4^-(aq) + NH^+_4(aq)$
1. 1.Define a Brønsted-Lowry acid and a Lewis acid.
2.Deduce the two species acting as acids and their conjugate bases in the equation above.
2.Give an example of a species that is a Lewis acid but not a Brønsted-Lowry acid and explain why this is the case.

  Which of the following solutions,;jfjg6 aqb;2m when mixed with equal volumes at equal concentratg26jj;;m ab qfions, form a buffer solution?

  $10\,cm^3$ of an aqueous solution of HCl with pH 1.0 is mixed with $990\,cm^3$ of water. The pH of the formed solution is:

  $20\,cm^3$ of $0.100\,mol\,dm^{-3}$ NaOH were slowly added to a $10\,cm^3$ sample of $0.100\,mol\,dm^{-3}$ HCl,and the pH was measured throughout the addition.
The equation for the reaction is as follows: $NaOH(aq) + NCl(aq) \rightarrow NaCl(aq) + H_2O(l)$
The ionic product constant of water at $25^{\circ}C$ is $1.00\times10^{-14}$
1.Calculate the number of moles of NaOH remaining at the end of the addition.Mole ratio is 1:1 and NaOH is in excess by  $\times10^{-3}\,mol$
2.Calculate the concentration of $OH^-$ at the end of the addition.  $mol\,dm^{-3}$
3.Using your value for $[OH^-]$ in (b), calculate the pH of the solution at the end of the addition.  

  Concentrated sulfuric 04jp7ne1u*cc 1qmgpcn f6b yn1c96t macid behaves as a strong acid when it reacts with water:
$H_2SO_4(aq) \rightarrow H^+(aq) + HSO^-_4(aq)$
$HSO_4^- \rightleftharpoons H^+(aq) + SO_4^{2-}(aq)$
Which of the following is (are) true for $1.0\,mol\,dm^{-3}$ of sulfuric acid?
I.$[H^+]$ is high
II.$[SO_4^{2-}]$ is high
III.$[SO_4^{2-}] = [HSO^-_4]$

  Which indicator would be most suitable for a titration betwe6b//z3jvr -s i31nwrouzk/edz t (y9q en sodium hydroxide and ethanoici/d(y/v6 obkj/3n sr3t-ew z1z qz u9r acid?

Indicator	pKa
Methyl orange	3.7
Bromocresol green	4.7
Bromothymol blue	7.0
Phenolphthalein	9.6

  Which statements arewx23 (kht, zdz correct?
I.$CH_3NH_2$ is a Lewis base
II.HOOCCOOH is a Bronsted-Lowry acid
III.$CH^+_3$ is a Lewis acid

  Methanoic acid HCOOH is a weck+yf0v5 w*vmvrn35;nfa(v uak acid.
1.State the formula of the conjugate base of HCOOH.
2.HCl is a strong acid and dissociates in water as shown below:
$HCl(aq) \rightarrow H^+(aq) + Cl^-(aq)$
1.Suggest the pH of the solution formed when HCl dissolves in water.
2.Compare the relative strengths of the respective conjugate bases of HCOOH and HCl.\ce{pH}pH value less than  
3.$0.01\,mol\,dm^{-3}$ of a given monoprotic acid HA has a pH of 3.
1. This acid is  ----待选择----weakstrong .
2.Compare the electrical conductivity of HA(aq) and $HNO_3(aq)$, giving a reason for your choice.

  Which statement about the equivalence point of acid-base titrations is lq1:+ppd16plto; q fkincorrect?+ 6qlk: t1ofq ;lpp1pd

  Which of the following salts form basic solutions when dissolved xy gy:8mg(ln4in water?
I.$NH_4Cl$
II.$K_2CO_3$
III.$NaOOCCH_3$

  Which of the following c)uzc3e9d7gec c /ga m.ombinations of $NH_3(aq)$ and HCl(aq) forms a buffer solution?

  The correct sequence in decreasine sej k)zg16z:g order of pH for equimolar solutions is:

  Which of the three oxides of period 3 below will cause a change in the pH of th,k5+0*k)kj ipy ffknhe solution when they react with wp k f)kk0*h5 ,fjikny+ater?
I.$Na_2O$
II.$SiO_2$
III.$P_4O_{10}$

1. 1.Differentiate between a strong acidz1e/ft l 5i8u4vuepr+j8akj8 and a weak acid.
2.State a balanced equation for the reaction between KOH and $HNO_3$.
Measuring the pH can be useful when trying to differentiate between different solutions.
A student has three unlabelled bottles of white powders. They know that the bottles contain either $KOH,KOOCCH_3 or HNO_3$.The student has access to a pH meter and distilled water.
2.Outline how the student can determine which powder is inside each of the three unlabelled bottles. Include equations where relevant.

  Four features of the t-zmn/j;8 ze hmyz 7n3$HNO_3$ molecule are labelled a-d.

Why is one mole of $HNO_3$ able to react with one mole of NaOH?

  Which of the following stagay, . xrdkt51tements about pH is incorrect?

Ethanoic acid reacts with trimethylamine to produq:4vd;ry a/vo ju-j 0mce a negatively charged ethanoate ion and another jm-:d/yjaqvrou; 4 v0charged compound X.


1.Ethanoic acid and the ethanoate ion differ by one hydrogen ion. State the name given to a pair of molecules that differ in this way.
2.State why trimethylamine is categorised as a Brønsted-Lowry base.
3.Ethanoic acid can be represented as $CH_3COOH$. This formula provides a better description of the bonding in the molecule than the alternative formula $CH_3CO_2H$.
1.Suggest why it is better to represent the structure of ethanoic acid as $CH_3COOH$ than as $CH_3CO_2H$.
2.The formula of compound X is $(CH_3)_3NH^+$.Draw the structural formula of compound X.
4.Water can react with both ethanoic acid and trimethylamine.
1.The reaction of water with ethanoic acid produces an ethanoate ion and another charged compound Y. State the formula of compound Y.
2.State the property of water and trimethylamine that allows them both to react with Brønsted-Lowry acids.

  Which of the following acid-base pairs are coro-un+liqw fi cces(w5y d-8c1 au5o7- rectly matched with the salt formed froua5-y17sd8c f-ociul ne-wqi+5c wo(m their reaction?

This question is about the weak acid, carng,3iy :v2ik*xde *62aot di kbonic acid $H_2CO_3(pK_{a1} = 6.35)$.
1. 1.Determine the pH of a $0.175\,mol\,dm^{-3}$ solution of carbonic acid.
2.State one assumption made in your answer to (a)(i).
Carbonic acid is a diprotic acid so can undergo two dissociations. The second dissociation has a $pK_{a2}$ of 10.33.
2. 1.State the equation for the second dissociation of carbonic acid.
2.Comment on the degree of dissociation for this second proton, based on the value of $pK_{a2}$.

  Indicators are used to determine the endpoipq zx 09ouu2.int of a titration.
1.Using a relevant equation, explain how acid-base indicators work.
2. 1.Calculate the pH of a $1.0\,mol\,dm^{-3}$ solution of KOH.pH=  
2.Calculate the pH of a $0.5\,mol\,dm^{-3}$ solution of $HNO_3$.pH=  
3.Using section 22 (Section 18- 2025 Syllabus) of the data booklet, suggest a suitable acid-base indicator for a titration between the solutions in (b)(i) and (b)(ii).
4.On the following axis, sketch the titration curve for the titration between the solutions in (b)(i) and (b)(ii), starting with $10\,cm^3$ of $HNO_3$ solution in the flask, and titrating with KOH.

  Commercial vinegar contains a +h:c k0 apsnm0..balgsmall percentage of ethanoic acid. A student wishes to determine the concentration of ethanoic acid in vinegar. She titrates a solution of ethanoic acid against a standard solution of potassisc:lmg.+kba a 0 .hn0pum hydroxide of concentration $8.0\times 10^{-4}\,mol\,dm^{-3}$. The equation for the reaction is:
$CH_3COOH(aq) + KOH(aq) \rightarrow CH_3COOK(aq) + H_2O(I)$
A volume of $25.0\,cm^3$ of vinegar was diluted with distilled water and made up to a volume of $250.0\,cm^3$ in a volumetric flask. A burette was filled with the diluted solution.
$25.0cm^3$ of potassium hydroxide solution was added to a conical flask and three drops of phenolphthalein indicator added.
1.Ethanoic acid is considered a weak acid. Define the term ‘weak acid’.
2.The results of the titration are shown in the table below:

Trial	Volume of Titre$(cm^3)$
1	21.0
2	21.2
3	20.8

1.Using section 22 (Section 18- 2025 Syllabus) of the IB data booklet, identify the color at the endpoint.
2.Calculate the concentration of dilute ethanoic acid.  
3.Calculate the concentration of ethanoic acid in vinegar.  $\times10^{-4}\,mol\,dm^{-3}$
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

  Which of the following equations is not an acid-ba*r jim5rji0 m8se reaction according to the Bronsted-Loii* rmj0j8r5mwry theory?

Zinc(II) oxide reacts with hydrochloric acid to prox o-m6g7v du)u)egt)rv *)bt rduce an aqueous solution of zinc and chlorideuv)m)7-d *gt vut )rx6rgeb o) ions.
$ZnO(s) + 2HCl(aq) \rightarrow Zn^{2+}(aq) + 2Cl^-(aq) + H_2O(I)$
1.HCl is described as an acid because it is a hydrogen ion donor. State the term used to describe acidity of this type
2.State the conjugate base of HCl in this reaction, giving a reason for your answer.
3.An aqueous solution of HCl does not contain molecules of HCl. Draw the structural formula of the positively charged molecule formed in the solution, including the positive charge.
4.Zinc(II) oxide is amphoteric.
1.Define the term amphoteric.
2.Suggest a reaction that could be performed to confirm that zinc oxide is amphoteric, giving your reasoning.
3.Explain why zinc(II) oxide is not amphiprotic.

$H_2O$ is an example of an amphiprotic species meaning it can act as either an acid or base.
1. 1.Draw the Lewis structure of $H_2O$.
2.Explain why $H_2O$ can act as both a Brønsted-Lowry acid and Brønsted-Lowry base.
3.Explain why $H_2O$ can act as a Lewis base.
2. 1.State an example of an acid-base reaction where $H_2O$ acts as a Brønsted-Lowry acid and another where $H_2O$ acts as a Brønsted-Lowry base.
2.State an example of a Lewis acid-base reaction that is not a Brønsted-Lowry acid-base reaction where $H_2O$ acts as a Lewis base.

  When powdered calcium oxide is added to h k)6rwf;:im4d (x,n9 ajv f+vfp ylw0dilute hydrochloric acid in a conical flask, the products are water, positive calcium ions and nwh:k) p 9v6y+i r;a,(4vfl0jdx nwffmegative chloride ions.



Which species is the conjugate base of hydrochloric acid in this reaction?

  A bottle contains dilute ethanoic aci+9zl:d3 i9kvc hmvz;khia -d- d $CH_3COOH$ of unknown concentration. To determine the concentration of the acid, a student titrates the acid against a standard solution of KOH according to the following equation:
$CH_3COOH(aq) +KOH(aq) \rightarrow CH_3COOK(aq) + H_2O(I)$
1.Calculate the mass of KOH that must be used to prepare $400.0\,cm^3$ of a $0.100\,mol\,dm^{-3}\,KOH$ solution.n=  mol , m=  g
2.Calculate the pH of the $0.100\,mol\,dm^{-3}\,KOH$ solution given that it ionizes completely in solution as shown in the following equation: $KOH(aq) \rightarrow K^+(aq) + OH^-(aq)$ pH=  
3.During the titration, the student finds that exactly $20.0\,cm^3$ of the KOH solution neutralizes exactly $25.0\,cm^3$ of the $CH_3COOH$ solution. Calculate the concentration of the $CH_3COOH$ solution.C=  $mol\,dm^{-3}$

  Hydrogen sulfide,$H_2S$, is a weak acid with a $pK_a$ of 7.04.
1.1.State the acid dissociation constant expression for $H_2S$.
2.Calculate $K_a$ for $H_2S$.  $\times 10^{-8}$
2.1.State the base dissociation constant expression for $HS^-$.
2.Calculate $K_b$ for $HS^-$ assuming a temperature of 298K.  $\times 10^{-7}$
3.Using your answers to parts (a)(i) and (b)(i), derive the equation $K_w =K_a \times K_b$

  Which quantities are required to calcz,;ru5 vono+-gicxy.6.3 jbhfsdt t:vp(k)w ulate the pH of a solution of a monoprotic we-5t)s.+z 6vfrpdwx o by3hk(.n,ucgivo:;tj ak acid?
I.The $pK_a$ of the weak acid
II.The concentration of the solution
III.The value of $K_w$

1.State the complete balanced equatiook ne- vi/:u)in for the reaction between sulphuric acid and copper (II) k i on/)uv-i:eoxide.
2.State the complete balanced equation for the reaction between ethanoic acid and potassium carbonate.
3.Outline two ways to monitor the rate of reaction for reaction (b) above.

  Acids and bases can be classi 1h 4 nsf4-*ka+n+n hxrfr0 nse8*,j,pgsv dcpfied as strong or weak.
1.Explain why ammonia,$NH_3$ in an aqueous solution, acts as a weak base, using an equation.
2.An experiment was carried out to determine the energy change during the following reaction:
$2NH_3(aq) + H_2SO_4(aq) \rightarrow (NH_4)_2SO_4(aq)$
Initial temperature of each solution =$21.4^{\circ}C$
Final temperature of the mixture = $23.8^{\circ}C$
1.State with a reason whether the sign of the enthalpy change for this reaction is positive or negative.
2.Suggest with a reason whether the magnitude of the enthalpy change will be  ----待选择----greatersmaller  if aqueous ammonia is replaced with potassium hydroxide.
​

The Brønsted-Lowry and the Lewis theories are two difpyyt;g7f9xxn7+g;v)4e b 1mvi5tmw x5 h0 mh cferent theories of classifying acig ;m hmtn5gb )0h 51evxtmv;yifc xxp79+ 47ywds and bases.
1. 1.Distinguish between the Brønsted-Lowry theory and the Lewis theory.
2.Define incomplete octet.
Consider the dimerization of $AlCl_3$:
$2AlCl \rightarrow 3Al_2Cl_6$
2. 1.Draw structural formulas to represent this reaction.
2.Explain how this is an acid-base reaction under the Lewis theory but not the Brønsted-Lowry theory.

  The pH of a $0.1\,mol\,dm^{-3}$ solution of phenol is 5.0. What is the approximate $K_a$ of phenol?

  A student reacts a $15\,cm^3$ sample of $0.10\,mol\,dm^{-3}$ methylamine,$CH_3NH_2(K_b = 4.47\times 10^{-4})$,with $10\,cm^3$ of $0.10\,mol\,dm^{-3}\,HNO_3$.
1. 1.Calculate the initial number of moles of methylamine in the sample.$n(CH_3NH_2)_{initial}$ =   $\times 10^{-3}$
2.Calculate the final number of moles of methylamine after the neutralization reaction.
2.Calculate the pOH of the final solution.pOH=  

Aqueous ammonia solutions are commonly used to c: q 2puz621rzg1jkx xclean in houses, particularly glass such as windows. There are many safety warnings on trq jxk2:x1ugpzz16 c2 hese products.
1.Ammonia mixed in water forms ammonium hydroxide. State the equation for this process.
2.One concern is that ammonia solutions could mix with acidic cleaning products, such as drain cleaner with sulphuric acid.
1.Determine the balanced equation for ammonium hydroxide reacting with sulphuric acid.
2.Suggest a reason this reaction could be dangerous.

  The function of the acid-base i1jx9zme. g)ftndicator, In, can be expressed using the equation belowmfz.e)9j tgx 1
$In + H_2O \rightleftharpoons InH^+ + OH^-;K_c = 35
Blue Yellow
Which of the below statements are correct?
I.The solution becomes darker blue with the addition of an acid
II.The solution is a pale green at equilibrium
III.$K_c$ increases with the addition of an alkali

In the amino acid glycine, a;fr1dduc l k9qs8q,67k pf*hi hydrogen ion may be transferred from one part of the molecule to anc s*ul7qq, d k;ip9fdfh1rk86other as shown.



In this reaction, glycine acts as both a Brønsted-Lowry acid and a Brønsted-Lowry base.
1.State the part of the glycine molecule that acts as a Brønsted-Lowry acid in the forward reaction, giving a reason for your answer.
2.In an aqueous solution of glycine, the transfer of the hydrogen ion may involve two reaction steps. The first reaction step is shown.


(i)By considering how a hydrogen ion forms from a hydrogen atom, explain why the hydrogen ion is often referred to as a proton.
(ii)Explain why $H^+$ is not an accurate representation of the cation formed in this reaction.
3.Amino acids such as glycine can be used to produce long molecules called peptides. The shape of the peptide molecule is determined by the types of intermolecular interactions present between the amino acid side chains, which have different structures. Part of a peptide molecule is shown, with the side chains highlighted in bold.


Suggest why acid-base reactions could alter the shape of this peptide chain.

  Which of the following is a catlygr+26 i9 0h- smfxonjugate acid-base pair?