An example of a stroz ncgi(is7r l1b4 gg0(l ,c5kmng acid solution is nitric acid. Which statement is correct for this sol g(nicgli7krlzbm (0541, gcs ution?

  Which of the following statements concerning acids and bases is not true? zcct(kfp-es9vtu;l+tf 83 ;i

  Which of the following 2 k rrtlf0fl hz/jv8v1 sy95t:is correct?

  Which statement about ao ua6*dp oy79x strong acid and its conjugate base is correct?

  Which of the followinjm/7ja -d dui: 66pzjdg expressions for $K_w$ is correct?

  Which combination of aci0rxlzr;5h yf7 d and base should be reacted to obtain a basic salt?

  A reaction produces carbon dioxide gas and a solution of pb8r 7rz 7ljz4a)2 sa :p*lfg37lqoegwater with a dissolved salt. What could be the rea7p7pa*8 3lag7 :gs2z)fejq4 orrll zbctants?

  Which combination of acid and base will typically have the lowest pH at theydrb 3;l nw lm0) gugu.kl.*ushc-0s, equivalencub)ul,s -00 c.d u*k3yngw ;.lrlmhgs e point in a titration?

  In order to prepare 3e8/k:;gc5z xp sjvh n,r,vap a solution of $0.1mol\:dm^{-3}$ with the highest pH, substance XX is dissolved in water. Substance X is

  Water dissociates partially and 0wt 5+)t,x bk88yj8-ks qw7udfr j kjwthe value of the ionic product constant of waterkjy5,u8b0x tw7kd -k w88jfw +qtrs )j at $25^{\circ}$ is $1.00\times10^{-14}$.
1.State an equation for the dissociation of water.
2.Calculate the pH of a $0.0100mol\:dm^{-3}$ of lithium hydroxide at 298K.  
3.Explain whether a $0.0100mol\:dm^{-3}$ solution of calcium hydroxide will have a higher or lower pH than a $0.0100mol\:dm^{-3}$ solution of lithium hydroxide at the same temperature.  $mol\:dm^{-3}$

  When wine is exposed to air, the ethanol is slowly /dat,tbl ;vj6 converted to ethanoic acid. The \ce{pH}pH of a6t,abdtj/vl; bottle of wine changes from 6.5 to 4.5. The concentration of $[H]^+$ is?

  A molecule of HBr reacts p5y. )o1u ro6dyq fy7yh6fk,iwith water to produce the charged molecule X. What is the Lewuodyqprfif1k6h6y,7 o5y y). is structure of molecule X?

  Alkali solutions can be made by dissolving a basico h g p8;rr)05eofm*a8nvjdzcy2k4v. substance in water.
1.Determine the concentration of a solution of NaOH made by carefully dissolving 5.00 g of NaOH in sufficient distilled water to make $250.0cm^3$ total solution in a volumetric flask.  $mol\:dm^{-3}$
2.An indicator was added to the solution made in (a), and it turned red. Using section 22 (Section 18- 2025 syllabus) in the Data booklet, state a possible indicator used.
3.The temperature of a $50.0cm^3$ sample of the solution containing the indicator from (b) was found to be $22.0^{\circ}C$. Suggest with a reason, two possible observations if a slightly larger quantity of HCl was added and stirred.
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers for the 2025 syllabus.

  An aqueous solution of niu, ysp72 sa9whv xd-:ftric acid $HNO_3$ has a pH of 4. How many moles of this acid are found in $1 dm^3$ of the solution?

  Which one of the following statement cf 609c xlc0fg0xs+fc4ks:xxs about acids is/are true?
|. Acids will neutralize bases to form salts
||. Acids produce solutions with pH greater than 7
|||.Acids ionize to form $H^+$ ions when dissolved in water

  What statements about indicators are cor sw-n4nv4o xt +c7ce)w slqpt,,6cp u,rect?
|.Indicators are typically weak acids or weak bases
||.Indicators are different colours in acidic and alkaline conditions
|||.The midpoint of the colour change of an indicator occurs when [$HIn$] = [$In^-$]

  A solution of $1.0\:mol\:dm^{-3}$ HCl is diluted to $0.1\:mol\:dm^{-3}$. Which statement is correct?

  Which expression repre/drkt e,2: gu vc;:fvj+kip/ysents $K_a$ for $CH_3COOH$?

  Given the following indicatj(l,d l o hk.vb2-mmn9ors and their behaviours, what will be the correct colours of a solmjklbd.on-9 m(2lv,hution of 1.0 M KOH tested with each indicator?

Indicator	pH range	Colour change (Acid- alkali)
Methyl orange	3.1- 4.4	Red – Orange
Bromocresol green	3.8 - 5.4	Yellow - Blue
Phenolphthalein	8.3 - 10.0	Colourless - Pink

  What is the order of increasing acid strengtcn/t t;ey.s8 mh based on the $pK_a$ values below?

Acid	$pK_a$
$CCI_3COOH$	0.66
$HCOOH$	3.75
$C_6H_5OH$	9.99
$CH_3OH$	15.5

  The structure of the hydrogen phosphate i b-c;4hk6f p)iyabn7tg bl:vc ky* 1(non is shown.


How many $H^+$ ions can react with one hydrogen phosphate ion?^+ions can react with one hydrogen phosphate ion?

  Place the following xm) h3di iim h qrmfs o*7qpp.3x4mw3./ q,2uq$1.0\,mol\:dm^{-3}$ solutions in order of increasing pH:
$NaOH,Na_2CO_3,NaCl$

  Which of the following reactio n3kptwyo06w.hqx u yct5z 5s1881hxjns is not a neutralization reaction?

One example of an important buffer s.djk1h u :w 1e1 ic.9vt4p+y,fo,i,w gdnzactystem is the $H_2CO_3/HCO_3^-$ buffer in our blood.
1. 1.Define buffer solution.
2.Using relevant equations, describe how the $H_2CO_3/HCO_3^-$ buffer works.
A student has solutions of $0.5\,mol\,dm^{-3}$ $NaOH,HCl,H_2CO_3andNaHCO_3$.
2.State two ways the $H_2CO_3/HCO_3^-$buffer can be made from these solutions.

  The reversible react9mff5k qjz/ 0zh ln 8uwg3js7(ion between $NH_3$ and $H_2SO_4$ is:
$NH_3 + H_2SO_4 \rightleftharpoons NH^+_4 + HSO_4^-$
Which compounds act as bases in the forward and backward reactions?

  What is the pH of a -gz,, ruirdp 0$0.001\,mol\,dm^{-3}$ aqueous solution of KOH at 298K given that it ionizes completely?

Consider the following reactiol ny)gkjsl703 ute*a v p-g5u-n:
$H_2SO_4(aq) + NH_3(aq) \rightleftharpoons HSO_4^-(aq) + NH^+_4(aq)$
1. 1.Define a Brønsted-Lowry acid and a Lewis acid.
2.Deduce the two species acting as acids and their conjugate bases in the equation above.
2.Give an example of a species that is a Lewis acid but not a Brønsted-Lowry acid and explain why this is the case.

  Which of the following solutions, when mixe) 6qye0occ x;kdqnxe( 0 l)np0d with equal volumes at equal concentratiqc n;) 6x 0cpdno()0yx 0lekeqons, form a buffer solution?

  $10\,cm^3$ of an aqueous solution of HCl with pH 1.0 is mixed with $990\,cm^3$ of water. The pH of the formed solution is:

  $20\,cm^3$ of $0.100\,mol\,dm^{-3}$ NaOH were slowly added to a $10\,cm^3$ sample of $0.100\,mol\,dm^{-3}$ HCl,and the pH was measured throughout the addition.
The equation for the reaction is as follows: $NaOH(aq) + NCl(aq) \rightarrow NaCl(aq) + H_2O(l)$
The ionic product constant of water at $25^{\circ}C$ is $1.00\times10^{-14}$
1.Calculate the number of moles of NaOH remaining at the end of the addition.Mole ratio is 1:1 and NaOH is in excess by  $\times10^{-3}\,mol$
2.Calculate the concentration of $OH^-$ at the end of the addition.  $mol\,dm^{-3}$
3.Using your value for $[OH^-]$ in (b), calculate the pH of the solution at the end of the addition.  

  Concentrated sulfuric acid behaves aso5.mzt)pjs*x2+t3 m:d js6t 0s ajyxe a strong acid when it reacts with water:
$H_2SO_4(aq) \rightarrow H^+(aq) + HSO^-_4(aq)$
$HSO_4^- \rightleftharpoons H^+(aq) + SO_4^{2-}(aq)$
Which of the following is (are) true for $1.0\,mol\,dm^{-3}$ of sulfuric acid?
I.$[H^+]$ is high
II.$[SO_4^{2-}]$ is high
III.$[SO_4^{2-}] = [HSO^-_4]$

  Which indicator would8afu s9t k.3 ods .v/y)d-nnaj be most suitable for a titration between sodium hydroxide and ethanoic acid? d9uano)df..k y8-snj v/ta3 s

Indicator	pKa
Methyl orange	3.7
Bromocresol green	4.7
Bromothymol blue	7.0
Phenolphthalein	9.6

  Which statements are cm lzwe8o( d)0ux;l: t28syuhmorrect?
I.$CH_3NH_2$ is a Lewis base
II.HOOCCOOH is a Bronsted-Lowry acid
III.$CH^+_3$ is a Lewis acid

  Methanoic acid HCOOH is a w2exl:8,bmh zucb8 )xweak acid.
1.State the formula of the conjugate base of HCOOH.
2.HCl is a strong acid and dissociates in water as shown below:
$HCl(aq) \rightarrow H^+(aq) + Cl^-(aq)$
1.Suggest the pH of the solution formed when HCl dissolves in water.
2.Compare the relative strengths of the respective conjugate bases of HCOOH and HCl.\ce{pH}pH value less than  
3.$0.01\,mol\,dm^{-3}$ of a given monoprotic acid HA has a pH of 3.
1. This acid is  ----待选择----weakstrong .
2.Compare the electrical conductivity of HA(aq) and $HNO_3(aq)$, giving a reason for your choice.

  Which statement about the equivalence point of acid-s36gkv p0ysn, iuy7i kz z z82sap39*jbase titrations is incorrectk3zv7yps*uip8y3 n 09s z,zi 6jkg2as?

  Which of the following salts form basic solutions wh+mqo0 f*c pw zy/3g2ruen dissolved in water?
I.$NH_4Cl$
II.$K_2CO_3$
III.$NaOOCCH_3$

  Which of the following combinations of )xod yfr3u1leo 55c8rs v9au* $NH_3(aq)$ and HCl(aq) forms a buffer solution?

  The correct sequence in decreasing order of pH for equimolar solutions isp5ie978 f.z / cg/cv;hbvw4db ak(4r uy9yvug:

  Which of the three oxidesxdqzyjq(*4,2dl nvc 3 of period 3 below will cause a change in the pH of the solution when they react with water? xcqyv3q( *znd2,l jd4
I.$Na_2O$
II.$SiO_2$
III.$P_4O_{10}$

1. 1.Differentiate between a strong acid and a ;(j -u x kmv+42a6lk9q rn18soybrlgfweak acid.
2.State a balanced equation for the reaction between KOH and $HNO_3$.
Measuring the pH can be useful when trying to differentiate between different solutions.
A student has three unlabelled bottles of white powders. They know that the bottles contain either $KOH,KOOCCH_3 or HNO_3$.The student has access to a pH meter and distilled water.
2.Outline how the student can determine which powder is inside each of the three unlabelled bottles. Include equations where relevant.

  Four features of the f1s -8 yvn-e.rjd2d cn$HNO_3$ molecule are labelled a-d.

Why is one mole of $HNO_3$ able to react with one mole of NaOH?

  Which of the following stat3x.: 3l cx ha7-xhbceaements about pH is incorrect?

Ethanoic acid reacts with trimethylamine to produce a negatively charged etha 3 kpm,h(8nfkmnoate ion and another charged3fkmpnm ,(kh 8 compound X.


1.Ethanoic acid and the ethanoate ion differ by one hydrogen ion. State the name given to a pair of molecules that differ in this way.
2.State why trimethylamine is categorised as a Brønsted-Lowry base.
3.Ethanoic acid can be represented as $CH_3COOH$. This formula provides a better description of the bonding in the molecule than the alternative formula $CH_3CO_2H$.
1.Suggest why it is better to represent the structure of ethanoic acid as $CH_3COOH$ than as $CH_3CO_2H$.
2.The formula of compound X is $(CH_3)_3NH^+$.Draw the structural formula of compound X.
4.Water can react with both ethanoic acid and trimethylamine.
1.The reaction of water with ethanoic acid produces an ethanoate ion and another charged compound Y. State the formula of compound Y.
2.State the property of water and trimethylamine that allows them both to react with Brønsted-Lowry acids.

  Which of the following acid-base pairs are c6d /pmupfk1s 1orrectly matched with the salt formed from theirsp1p1d fkmu6/ reaction?

This question is aboqd2fmw8lw 3-;zezyiz);h 1 bvb. pk9x1u yo b)ut the weak acid, carbonic acid $H_2CO_3(pK_{a1} = 6.35)$.
1. 1.Determine the pH of a $0.175\,mol\,dm^{-3}$ solution of carbonic acid.
2.State one assumption made in your answer to (a)(i).
Carbonic acid is a diprotic acid so can undergo two dissociations. The second dissociation has a $pK_{a2}$ of 10.33.
2. 1.State the equation for the second dissociation of carbonic acid.
2.Comment on the degree of dissociation for this second proton, based on the value of $pK_{a2}$.

  Indicators are used to determine the endpoint oi)jz b - bm,2et.vwao)f a titration.
1.Using a relevant equation, explain how acid-base indicators work.
2. 1.Calculate the pH of a $1.0\,mol\,dm^{-3}$ solution of KOH.pH=  
2.Calculate the pH of a $0.5\,mol\,dm^{-3}$ solution of $HNO_3$.pH=  
3.Using section 22 (Section 18- 2025 Syllabus) of the data booklet, suggest a suitable acid-base indicator for a titration between the solutions in (b)(i) and (b)(ii).
4.On the following axis, sketch the titration curve for the titration between the solutions in (b)(i) and (b)(ii), starting with $10\,cm^3$ of $HNO_3$ solution in the flask, and titrating with KOH.

  Commercial vinegar contains a small percentage ofdeak5 g57k iv2 ethanoic acid. A student wishes to determine the concentration of ethanoic acid in vinegar. She titrg 5v 5k2eak7idates a solution of ethanoic acid against a standard solution of potassium hydroxide of concentration $8.0\times 10^{-4}\,mol\,dm^{-3}$. The equation for the reaction is:
$CH_3COOH(aq) + KOH(aq) \rightarrow CH_3COOK(aq) + H_2O(I)$
A volume of $25.0\,cm^3$ of vinegar was diluted with distilled water and made up to a volume of $250.0\,cm^3$ in a volumetric flask. A burette was filled with the diluted solution.
$25.0cm^3$ of potassium hydroxide solution was added to a conical flask and three drops of phenolphthalein indicator added.
1.Ethanoic acid is considered a weak acid. Define the term ‘weak acid’.
2.The results of the titration are shown in the table below:

Trial	Volume of Titre$(cm^3)$
1	21.0
2	21.2
3	20.8

1.Using section 22 (Section 18- 2025 Syllabus) of the IB data booklet, identify the color at the endpoint.
2.Calculate the concentration of dilute ethanoic acid.  
3.Calculate the concentration of ethanoic acid in vinegar.  $\times10^{-4}\,mol\,dm^{-3}$
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

  Which of the following equat/j:wl35 d0 ipspjh 7w 1j2ljvvions is not an acid-base reaction according to the Bronsted-Lowry tjp5:wlw7vj 1d30 lhijs2p vj/ heory?

Zinc(II) oxide reacts with hydrochloric acid to prom(-(yggz) 9)mg s ld7w:g tlcyduce an aqueous solution of zinc and chloridw(:zdcl 7yys( ggg)g9mml - t)e ions.
$ZnO(s) + 2HCl(aq) \rightarrow Zn^{2+}(aq) + 2Cl^-(aq) + H_2O(I)$
1.HCl is described as an acid because it is a hydrogen ion donor. State the term used to describe acidity of this type
2.State the conjugate base of HCl in this reaction, giving a reason for your answer.
3.An aqueous solution of HCl does not contain molecules of HCl. Draw the structural formula of the positively charged molecule formed in the solution, including the positive charge.
4.Zinc(II) oxide is amphoteric.
1.Define the term amphoteric.
2.Suggest a reaction that could be performed to confirm that zinc oxide is amphoteric, giving your reasoning.
3.Explain why zinc(II) oxide is not amphiprotic.

$H_2O$ is an example of an amphiprotic species meaning it can act as either an acid or base.
1. 1.Draw the Lewis structure of $H_2O$.
2.Explain why $H_2O$ can act as both a Brønsted-Lowry acid and Brønsted-Lowry base.
3.Explain why $H_2O$ can act as a Lewis base.
2. 1.State an example of an acid-base reaction where $H_2O$ acts as a Brønsted-Lowry acid and another where $H_2O$ acts as a Brønsted-Lowry base.
2.State an example of a Lewis acid-base reaction that is not a Brønsted-Lowry acid-base reaction where $H_2O$ acts as a Lewis base.

  When powdered calcium oxide is added to dilutqdn5p2 wgvu-( e hydrochloric acid in a conical flask, the products are water, qnv5pu -gd w(2positive calcium ions and negative chloride ions.



Which species is the conjugate base of hydrochloric acid in this reaction?

  A bottle contains dilute ethanoicjgk 0 8cjq9tp)m ,uy8z acid $CH_3COOH$ of unknown concentration. To determine the concentration of the acid, a student titrates the acid against a standard solution of KOH according to the following equation:
$CH_3COOH(aq) +KOH(aq) \rightarrow CH_3COOK(aq) + H_2O(I)$
1.Calculate the mass of KOH that must be used to prepare $400.0\,cm^3$ of a $0.100\,mol\,dm^{-3}\,KOH$ solution.n=  mol , m=  g
2.Calculate the pH of the $0.100\,mol\,dm^{-3}\,KOH$ solution given that it ionizes completely in solution as shown in the following equation: $KOH(aq) \rightarrow K^+(aq) + OH^-(aq)$ pH=  
3.During the titration, the student finds that exactly $20.0\,cm^3$ of the KOH solution neutralizes exactly $25.0\,cm^3$ of the $CH_3COOH$ solution. Calculate the concentration of the $CH_3COOH$ solution.C=  $mol\,dm^{-3}$

  Hydrogen sulfide,$H_2S$, is a weak acid with a $pK_a$ of 7.04.
1.1.State the acid dissociation constant expression for $H_2S$.
2.Calculate $K_a$ for $H_2S$.  $\times 10^{-8}$
2.1.State the base dissociation constant expression for $HS^-$.
2.Calculate $K_b$ for $HS^-$ assuming a temperature of 298K.  $\times 10^{-7}$
3.Using your answers to parts (a)(i) and (b)(i), derive the equation $K_w =K_a \times K_b$

  Which quantities are required to calculate the pH of a h;gmne4 mu6j, solution of a monoprotic wege4mun 6j;,m hak acid?
I.The $pK_a$ of the weak acid
II.The concentration of the solution
III.The value of $K_w$

1.State the complete balanced equation ff/4rv-7g3 tieeeh 8h kor the reaction between sulphuric acid an v8h -37f eegitk/4rhed copper (II) oxide.
2.State the complete balanced equation for the reaction between ethanoic acid and potassium carbonate.
3.Outline two ways to monitor the rate of reaction for reaction (b) above.

  Acids and bases can be classified ase6k 6(yjmtw 0* hssx2o strong or weak.
1.Explain why ammonia,$NH_3$ in an aqueous solution, acts as a weak base, using an equation.
2.An experiment was carried out to determine the energy change during the following reaction:
$2NH_3(aq) + H_2SO_4(aq) \rightarrow (NH_4)_2SO_4(aq)$
Initial temperature of each solution =$21.4^{\circ}C$
Final temperature of the mixture = $23.8^{\circ}C$
1.State with a reason whether the sign of the enthalpy change for this reaction is positive or negative.
2.Suggest with a reason whether the magnitude of the enthalpy change will be  ----待选择----greatersmaller  if aqueous ammonia is replaced with potassium hydroxide.
​

The Brønsted-Lowry and the Lewis theori1f zq,n3ft/jjz g90pkn15q v ees are two different theories of classifying acids 1fz95njz qnpvg3f1e k0,/ qtjand bases.
1. 1.Distinguish between the Brønsted-Lowry theory and the Lewis theory.
2.Define incomplete octet.
Consider the dimerization of $AlCl_3$:
$2AlCl \rightarrow 3Al_2Cl_6$
2. 1.Draw structural formulas to represent this reaction.
2.Explain how this is an acid-base reaction under the Lewis theory but not the Brønsted-Lowry theory.

  The pH of a $0.1\,mol\,dm^{-3}$ solution of phenol is 5.0. What is the approximate $K_a$ of phenol?

  A student reacts a $15\,cm^3$ sample of $0.10\,mol\,dm^{-3}$ methylamine,$CH_3NH_2(K_b = 4.47\times 10^{-4})$,with $10\,cm^3$ of $0.10\,mol\,dm^{-3}\,HNO_3$.
1. 1.Calculate the initial number of moles of methylamine in the sample.$n(CH_3NH_2)_{initial}$ =   $\times 10^{-3}$
2.Calculate the final number of moles of methylamine after the neutralization reaction.
2.Calculate the pOH of the final solution.pOH=  

Aqueous ammonia solutions are commonly used to clean in houses, particu0*r +pmj3df y e,6kpaelarly glass such as winj*e0p y63efd r+amp,kdows. There are many safety warnings on these products.
1.Ammonia mixed in water forms ammonium hydroxide. State the equation for this process.
2.One concern is that ammonia solutions could mix with acidic cleaning products, such as drain cleaner with sulphuric acid.
1.Determine the balanced equation for ammonium hydroxide reacting with sulphuric acid.
2.Suggest a reason this reaction could be dangerous.

  The function of the acid-base insyeu/sdmo9 u40u- 8uc dicator, In, can be expressed using the equation belcu-s8u m/o s d4u0yue9ow
$In + H_2O \rightleftharpoons InH^+ + OH^-;K_c = 35
Blue Yellow
Which of the below statements are correct?
I.The solution becomes darker blue with the addition of an acid
II.The solution is a pale green at equilibrium
III.$K_c$ increases with the addition of an alkali

In the amino acid glycine9c5 mybjije.2j jh 9.f, a hydrogen ion may be transferred from one part of the molecule to another as sho9.ejjyj9 mc2hbijf 5. wn.



In this reaction, glycine acts as both a Brønsted-Lowry acid and a Brønsted-Lowry base.
1.State the part of the glycine molecule that acts as a Brønsted-Lowry acid in the forward reaction, giving a reason for your answer.
2.In an aqueous solution of glycine, the transfer of the hydrogen ion may involve two reaction steps. The first reaction step is shown.


(i)By considering how a hydrogen ion forms from a hydrogen atom, explain why the hydrogen ion is often referred to as a proton.
(ii)Explain why $H^+$ is not an accurate representation of the cation formed in this reaction.
3.Amino acids such as glycine can be used to produce long molecules called peptides. The shape of the peptide molecule is determined by the types of intermolecular interactions present between the amino acid side chains, which have different structures. Part of a peptide molecule is shown, with the side chains highlighted in bold.


Suggest why acid-base reactions could alter the shape of this peptide chain.

  Which of the following aa9 khjdb7t* 62qyt)oia 48t eis a conjugate acid-base pair?