An example of a strong ad of 66rpjtygfj:x4 0i-m;c *pcid solution is nitric acid. Which statement is correct fo-x:g*f6 ij4r0 of jcympp dt;6r this solution?

  Which of the followingk mtg btrq1u,-6(1fi u statements concerning acids and bases is not true?

  Which of the following is-glga9 ndrb4 5 correct?

  Which statement about a strong acid and its conjugate base l0)n016xrar)awzhz8 kdhm d7 is correct?

  Which of the following expressiodu:,t;jf3b 9mwr (tok: gbi-uns for $K_w$ is correct?

  Which combination of acid and base should be recw 50q2zjt:n f . 5fanfy:bor8acted to obtain a basic salt?

  A reaction produces carbon dioxide gas and a solution of water wiu;xg*gx 8tp,d/5n,u vbxm7td th a dissolved salt. What tg8t g,db /u;xd7ux5mx *nvp,could be the reactants?

  Which combination of acid and base willkrk tqy9 .tc d6 p.q;3;taclp- typically have the lowest pH at the equivalence c;y akt;6pt 9lr-kpd 3.cqtq. point in a titration?

  In order to prepare a soluti ojne; hae,7f/wex3y 3on of $0.1mol\:dm^{-3}$ with the highest pH, substance XX is dissolved in water. Substance X is

  Water dissociates partially and the value of the ionic product c+ u5 d vw ( atik*j-h4ga35a.ea2iniwconstant of water a5wai*ae idci.gvu+ (w342k hn j5t-a at $25^{\circ}$ is $1.00\times10^{-14}$.
1.State an equation for the dissociation of water.
2.Calculate the pH of a $0.0100mol\:dm^{-3}$ of lithium hydroxide at 298K.  
3.Explain whether a $0.0100mol\:dm^{-3}$ solution of calcium hydroxide will have a higher or lower pH than a $0.0100mol\:dm^{-3}$ solution of lithium hydroxide at the same temperature.  $mol\:dm^{-3}$

  When wine is exposed to air, the ethanol is slowly coqh2woqq-t6 *-zv p)f enverted to ethanoic acid. The \ce{pH}pH of a bottle of wine changes -ow-hvteqq6qz*p 2)ffrom 6.5 to 4.5. The concentration of $[H]^+$ is?

  A molecule of HBr reacts with water to produc2c0yrm;+zw, xy5xit kpn0c- ve the charged molecule X. What is the Lewis stn0z05-r+cpw , icty m;kxxv 2yructure of molecule X?

  Alkali solutions can be made by dissolvinp: 3 twm6:yoesn 0 fprby0s /c67lhr5ng a basic substance in water.
1.Determine the concentration of a solution of NaOH made by carefully dissolving 5.00 g of NaOH in sufficient distilled water to make $250.0cm^3$ total solution in a volumetric flask.  $mol\:dm^{-3}$
2.An indicator was added to the solution made in (a), and it turned red. Using section 22 (Section 18- 2025 syllabus) in the Data booklet, state a possible indicator used.
3.The temperature of a $50.0cm^3$ sample of the solution containing the indicator from (b) was found to be $22.0^{\circ}C$. Suggest with a reason, two possible observations if a slightly larger quantity of HCl was added and stirred.
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers for the 2025 syllabus.

  An aqueous solution of ;3l ysv lrg8h;nitric acid $HNO_3$ has a pH of 4. How many moles of this acid are found in $1 dm^3$ of the solution?

  Which one of the following statements about acids is/areu+8 as2 99z pned fvu(qvznx37feda+ , true?
|. Acids will neutralize bases to form salts
||. Acids produce solutions with pH greater than 7
|||.Acids ionize to form $H^+$ ions when dissolved in water

  What statements about indicators ar9qo4oc kk;n83 wx* yave correct?
|.Indicators are typically weak acids or weak bases
||.Indicators are different colours in acidic and alkaline conditions
|||.The midpoint of the colour change of an indicator occurs when [$HIn$] = [$In^-$]

  A solution of $1.0\:mol\:dm^{-3}$ HCl is diluted to $0.1\:mol\:dm^{-3}$. Which statement is correct?

  Which expression rep69zrqw)kz5ej m1 qzb*resents $K_a$ for $CH_3COOH$?

  Given the following indica:cyto3qh h1 x8s2/p zwtors and their behaviours, what will be the correct colours of a soz3h/yh qx1tw28: c spolution of 1.0 M KOH tested with each indicator?

Indicator	pH range	Colour change (Acid- alkali)
Methyl orange	3.1- 4.4	Red – Orange
Bromocresol green	3.8 - 5.4	Yellow - Blue
Phenolphthalein	8.3 - 10.0	Colourless - Pink

  What is the order of increasing acid strength base0 xjiqazd9i: /7xt2 8* efmnl (cti*dgd on the $pK_a$ values below?

Acid	$pK_a$
$CCI_3COOH$	0.66
$HCOOH$	3.75
$C_6H_5OH$	9.99
$CH_3OH$	15.5

  The structure of the hydrogen phosphat(w(l7rl doat +e ion is shown.


How many $H^+$ ions can react with one hydrogen phosphate ion?^+ions can react with one hydrogen phosphate ion?

  Place the following xxs+ 69y rjm/q$1.0\,mol\:dm^{-3}$ solutions in order of increasing pH:
$NaOH,Na_2CO_3,NaCl$

  Which of the following reactions is not a neutralizationvuyl-y. 1fqil/k)ju, reaction?

One example of an importantc6kpkq5 srf d59 3oj1z buffer system is the $H_2CO_3/HCO_3^-$ buffer in our blood.
1. 1.Define buffer solution.
2.Using relevant equations, describe how the $H_2CO_3/HCO_3^-$ buffer works.
A student has solutions of $0.5\,mol\,dm^{-3}$ $NaOH,HCl,H_2CO_3andNaHCO_3$.
2.State two ways the $H_2CO_3/HCO_3^-$buffer can be made from these solutions.

  The reversible reaction between ,tklrdlkwjd eu6-vyw4k77) 8$NH_3$ and $H_2SO_4$ is:
$NH_3 + H_2SO_4 \rightleftharpoons NH^+_4 + HSO_4^-$
Which compounds act as bases in the forward and backward reactions?

  What is the pH of a o2n:rat(2f gw$0.001\,mol\,dm^{-3}$ aqueous solution of KOH at 298K given that it ionizes completely?

Consider the following g)kv1htxq2sj 9:r,sp reaction:
$H_2SO_4(aq) + NH_3(aq) \rightleftharpoons HSO_4^-(aq) + NH^+_4(aq)$
1. 1.Define a Brønsted-Lowry acid and a Lewis acid.
2.Deduce the two species acting as acids and their conjugate bases in the equation above.
2.Give an example of a species that is a Lewis acid but not a Brønsted-Lowry acid and explain why this is the case.

  Which of the following solutions, when mixed with equala1 u/gsm*sm9e 2*dv*tyqaqf 6 q: n.ik volumes at equal concentrations, form a buf d6q*favi*u*a 9yq/ :qgs2 m k1tems.nfer solution?

  $10\,cm^3$ of an aqueous solution of HCl with pH 1.0 is mixed with $990\,cm^3$ of water. The pH of the formed solution is:

  $20\,cm^3$ of $0.100\,mol\,dm^{-3}$ NaOH were slowly added to a $10\,cm^3$ sample of $0.100\,mol\,dm^{-3}$ HCl,and the pH was measured throughout the addition.
The equation for the reaction is as follows: $NaOH(aq) + NCl(aq) \rightarrow NaCl(aq) + H_2O(l)$
The ionic product constant of water at $25^{\circ}C$ is $1.00\times10^{-14}$
1.Calculate the number of moles of NaOH remaining at the end of the addition.Mole ratio is 1:1 and NaOH is in excess by  $\times10^{-3}\,mol$
2.Calculate the concentration of $OH^-$ at the end of the addition.  $mol\,dm^{-3}$
3.Using your value for $[OH^-]$ in (b), calculate the pH of the solution at the end of the addition.  

  Concentrated sulfuric acid behaves as a strong acid wheal73(hz1o p2aep+t 0ms/t l zf0-wxqmn it reacts with water:
$H_2SO_4(aq) \rightarrow H^+(aq) + HSO^-_4(aq)$
$HSO_4^- \rightleftharpoons H^+(aq) + SO_4^{2-}(aq)$
Which of the following is (are) true for $1.0\,mol\,dm^{-3}$ of sulfuric acid?
I.$[H^+]$ is high
II.$[SO_4^{2-}]$ is high
III.$[SO_4^{2-}] = [HSO^-_4]$

  Which indicator would be most suitable for a titration between sodiun-ia( 8pq;ec; 4kj+qh) eohaem hydroxide and ethanoic acqc;e8nqi) kh( ee+4p- ;oajhaid?

Indicator	pKa
Methyl orange	3.7
Bromocresol green	4.7
Bromothymol blue	7.0
Phenolphthalein	9.6

  Which statements are correukalvn1y 0dk).r. 9j am smv(4ct?
I.$CH_3NH_2$ is a Lewis base
II.HOOCCOOH is a Bronsted-Lowry acid
III.$CH^+_3$ is a Lewis acid

  Methanoic acid HCOOH is a 8o1nul+e0us3k k d7loweak acid.
1.State the formula of the conjugate base of HCOOH.
2.HCl is a strong acid and dissociates in water as shown below:
$HCl(aq) \rightarrow H^+(aq) + Cl^-(aq)$
1.Suggest the pH of the solution formed when HCl dissolves in water.
2.Compare the relative strengths of the respective conjugate bases of HCOOH and HCl.\ce{pH}pH value less than  
3.$0.01\,mol\,dm^{-3}$ of a given monoprotic acid HA has a pH of 3.
1. This acid is  ----待选择----weakstrong .
2.Compare the electrical conductivity of HA(aq) and $HNO_3(aq)$, giving a reason for your choice.

  Which statement about the equivalence point of acid-base titrations is inch .ts1h ++lwutorrect?htst wl+.h+1 u

  Which of the following salts form basic so9u 6+fl) xwubvlutions when dissolved in water?
I.$NH_4Cl$
II.$K_2CO_3$
III.$NaOOCCH_3$

  Which of the following combinations,ly6 j,7f/n 3 tshziag of $NH_3(aq)$ and HCl(aq) forms a buffer solution?

  The correct sequence in decreasing order of pH for equi qdtg tp7zh;+/molar solutions is:

  Which of the three oxides of period 3 below will cause a change in the pH 5yj9zaw(3lp r of the solution when they react with water? (rz 3jl p9a5wy
I.$Na_2O$
II.$SiO_2$
III.$P_4O_{10}$

1. 1.Differentiate between a strong acid and a weak6t :q4b/;icpga*b 0j3ojm2 lfkd-ec y acid.
2.State a balanced equation for the reaction between KOH and $HNO_3$.
Measuring the pH can be useful when trying to differentiate between different solutions.
A student has three unlabelled bottles of white powders. They know that the bottles contain either $KOH,KOOCCH_3 or HNO_3$.The student has access to a pH meter and distilled water.
2.Outline how the student can determine which powder is inside each of the three unlabelled bottles. Include equations where relevant.

  Four features of thefgn4c4dv/ba 8vtl 11 l $HNO_3$ molecule are labelled a-d.

Why is one mole of $HNO_3$ able to react with one mole of NaOH?

  Which of the following statements about p(lc17hec.i9:k6jib. 9xpl nh/udeueH is incorrect?

Ethanoic acid reacts with trimethylamine to produce a negatively charged ethano* oc:mumii .e(ate ion and another charged c:cu(mio *i.me ompound X.


1.Ethanoic acid and the ethanoate ion differ by one hydrogen ion. State the name given to a pair of molecules that differ in this way.
2.State why trimethylamine is categorised as a Brønsted-Lowry base.
3.Ethanoic acid can be represented as $CH_3COOH$. This formula provides a better description of the bonding in the molecule than the alternative formula $CH_3CO_2H$.
1.Suggest why it is better to represent the structure of ethanoic acid as $CH_3COOH$ than as $CH_3CO_2H$.
2.The formula of compound X is $(CH_3)_3NH^+$.Draw the structural formula of compound X.
4.Water can react with both ethanoic acid and trimethylamine.
1.The reaction of water with ethanoic acid produces an ethanoate ion and another charged compound Y. State the formula of compound Y.
2.State the property of water and trimethylamine that allows them both to react with Brønsted-Lowry acids.

  Which of the following acid-base pairs are cor3grph xz, )+d q*nz2/q4ompu urectly matched with the salt formed from their reactiuq2,odprmzh*zp n) 3/g +qxu4on?

This question is about the wedbwo2jrq 5c0h4 es ,oh7+kwk0ak acid, carbonic acid $H_2CO_3(pK_{a1} = 6.35)$.
1. 1.Determine the pH of a $0.175\,mol\,dm^{-3}$ solution of carbonic acid.
2.State one assumption made in your answer to (a)(i).
Carbonic acid is a diprotic acid so can undergo two dissociations. The second dissociation has a $pK_{a2}$ of 10.33.
2. 1.State the equation for the second dissociation of carbonic acid.
2.Comment on the degree of dissociation for this second proton, based on the value of $pK_{a2}$.

  Indicators are used to determineri v( 5vf,k go8j+kji2 the endpoint of a titration.
1.Using a relevant equation, explain how acid-base indicators work.
2. 1.Calculate the pH of a $1.0\,mol\,dm^{-3}$ solution of KOH.pH=  
2.Calculate the pH of a $0.5\,mol\,dm^{-3}$ solution of $HNO_3$.pH=  
3.Using section 22 (Section 18- 2025 Syllabus) of the data booklet, suggest a suitable acid-base indicator for a titration between the solutions in (b)(i) and (b)(ii).
4.On the following axis, sketch the titration curve for the titration between the solutions in (b)(i) and (b)(ii), starting with $10\,cm^3$ of $HNO_3$ solution in the flask, and titrating with KOH.

  Commercial vinegar contains a small percentk).ghw 4wm6tw,lmj(g age of ethanoic acid. A student wishes to determine the concentration of ethanoic acid in vinegar. She titrates a solution of ethanoic acid against a standard solutwghl)gj twkm4m.6,(w ion of potassium hydroxide of concentration $8.0\times 10^{-4}\,mol\,dm^{-3}$. The equation for the reaction is:
$CH_3COOH(aq) + KOH(aq) \rightarrow CH_3COOK(aq) + H_2O(I)$
A volume of $25.0\,cm^3$ of vinegar was diluted with distilled water and made up to a volume of $250.0\,cm^3$ in a volumetric flask. A burette was filled with the diluted solution.
$25.0cm^3$ of potassium hydroxide solution was added to a conical flask and three drops of phenolphthalein indicator added.
1.Ethanoic acid is considered a weak acid. Define the term ‘weak acid’.
2.The results of the titration are shown in the table below:

Trial	Volume of Titre$(cm^3)$
1	21.0
2	21.2
3	20.8

1.Using section 22 (Section 18- 2025 Syllabus) of the IB data booklet, identify the color at the endpoint.
2.Calculate the concentration of dilute ethanoic acid.  
3.Calculate the concentration of ethanoic acid in vinegar.  $\times10^{-4}\,mol\,dm^{-3}$
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

  Which of the following equations is not an acid-base c.eyq :;/ af2 -iun u8wi-xa6n0zgkni reaction according to the Bronsted-Lowry theue0c :a8i-ynwqxf k. innz2u6i;ag-/ ory?

Zinc(II) oxide reacts with hydrochloricpqg:7m y f 4; -fav8h u)pu9swi7pe2bx acid to produce an aqueous solution of zinc and chloride iowxp sm)hu429fye7uvfq- iga7pp; b 8:ns.
$ZnO(s) + 2HCl(aq) \rightarrow Zn^{2+}(aq) + 2Cl^-(aq) + H_2O(I)$
1.HCl is described as an acid because it is a hydrogen ion donor. State the term used to describe acidity of this type
2.State the conjugate base of HCl in this reaction, giving a reason for your answer.
3.An aqueous solution of HCl does not contain molecules of HCl. Draw the structural formula of the positively charged molecule formed in the solution, including the positive charge.
4.Zinc(II) oxide is amphoteric.
1.Define the term amphoteric.
2.Suggest a reaction that could be performed to confirm that zinc oxide is amphoteric, giving your reasoning.
3.Explain why zinc(II) oxide is not amphiprotic.

$H_2O$ is an example of an amphiprotic species meaning it can act as either an acid or base.
1. 1.Draw the Lewis structure of $H_2O$.
2.Explain why $H_2O$ can act as both a Brønsted-Lowry acid and Brønsted-Lowry base.
3.Explain why $H_2O$ can act as a Lewis base.
2. 1.State an example of an acid-base reaction where $H_2O$ acts as a Brønsted-Lowry acid and another where $H_2O$ acts as a Brønsted-Lowry base.
2.State an example of a Lewis acid-base reaction that is not a Brønsted-Lowry acid-base reaction where $H_2O$ acts as a Lewis base.

  When powdered calcium oxide is added to dilute hydrochloric acidf-eu6+qeu.lt/c,pn- 40aup ( c2kqxcsxf -to in a conical flask, the products are water, positive calci u,(/ e2x 4t-nt0kfe-aucq p cs ox.l-uqcp+f6um ions and negative chloride ions.



Which species is the conjugate base of hydrochloric acid in this reaction?

  A bottle contains dilu2he) v+kmpq 3nte ethanoic acid $CH_3COOH$ of unknown concentration. To determine the concentration of the acid, a student titrates the acid against a standard solution of KOH according to the following equation:
$CH_3COOH(aq) +KOH(aq) \rightarrow CH_3COOK(aq) + H_2O(I)$
1.Calculate the mass of KOH that must be used to prepare $400.0\,cm^3$ of a $0.100\,mol\,dm^{-3}\,KOH$ solution.n=  mol , m=  g
2.Calculate the pH of the $0.100\,mol\,dm^{-3}\,KOH$ solution given that it ionizes completely in solution as shown in the following equation: $KOH(aq) \rightarrow K^+(aq) + OH^-(aq)$ pH=  
3.During the titration, the student finds that exactly $20.0\,cm^3$ of the KOH solution neutralizes exactly $25.0\,cm^3$ of the $CH_3COOH$ solution. Calculate the concentration of the $CH_3COOH$ solution.C=  $mol\,dm^{-3}$

  Hydrogen sulfide,$H_2S$, is a weak acid with a $pK_a$ of 7.04.
1.1.State the acid dissociation constant expression for $H_2S$.
2.Calculate $K_a$ for $H_2S$.  $\times 10^{-8}$
2.1.State the base dissociation constant expression for $HS^-$.
2.Calculate $K_b$ for $HS^-$ assuming a temperature of 298K.  $\times 10^{-7}$
3.Using your answers to parts (a)(i) and (b)(i), derive the equation $K_w =K_a \times K_b$

  Which quantities are required to calculate the pcynm,il9us 1v+ p z; ut:7m4,r sl2juzH of a solution of a monoprotic weak acid? inu: +zv rm l4u mu;,27st yzcp9lj,1s
I.The $pK_a$ of the weak acid
II.The concentration of the solution
III.The value of $K_w$

1.State the complete balanced e,9rm (vl m w;yo; co2ctd-pbd.quation for the reaction between sulphuric acid and copper ;o (cvmcldw-rm; 2 ot.,dpyb9(II) oxide.
2.State the complete balanced equation for the reaction between ethanoic acid and potassium carbonate.
3.Outline two ways to monitor the rate of reaction for reaction (b) above.

  Acids and bases can be classifiez j7m4ud e*3eu)hyey6 d as strong or weak.
1.Explain why ammonia,$NH_3$ in an aqueous solution, acts as a weak base, using an equation.
2.An experiment was carried out to determine the energy change during the following reaction:
$2NH_3(aq) + H_2SO_4(aq) \rightarrow (NH_4)_2SO_4(aq)$
Initial temperature of each solution =$21.4^{\circ}C$
Final temperature of the mixture = $23.8^{\circ}C$
1.State with a reason whether the sign of the enthalpy change for this reaction is positive or negative.
2.Suggest with a reason whether the magnitude of the enthalpy change will be  ----待选择----greatersmaller  if aqueous ammonia is replaced with potassium hydroxide.
​

The Brønsted-Lowry and the Lewis theories are two different theories of clar8zy)t.bmxg: ssifying aztbr:y. g 8x)mcids and bases.
1. 1.Distinguish between the Brønsted-Lowry theory and the Lewis theory.
2.Define incomplete octet.
Consider the dimerization of $AlCl_3$:
$2AlCl \rightarrow 3Al_2Cl_6$
2. 1.Draw structural formulas to represent this reaction.
2.Explain how this is an acid-base reaction under the Lewis theory but not the Brønsted-Lowry theory.

  The pH of a $0.1\,mol\,dm^{-3}$ solution of phenol is 5.0. What is the approximate $K_a$ of phenol?

  A student reacts a $15\,cm^3$ sample of $0.10\,mol\,dm^{-3}$ methylamine,$CH_3NH_2(K_b = 4.47\times 10^{-4})$,with $10\,cm^3$ of $0.10\,mol\,dm^{-3}\,HNO_3$.
1. 1.Calculate the initial number of moles of methylamine in the sample.$n(CH_3NH_2)_{initial}$ =   $\times 10^{-3}$
2.Calculate the final number of moles of methylamine after the neutralization reaction.
2.Calculate the pOH of the final solution.pOH=  

Aqueous ammonia solutions are commonly uk5 pp7j7w+:ot3h- c4;mtmvdfgu+q f esed to clean in houses, particularly glass such as windows. There are many safet;gf 7mq ef kh:t-pm v+tw5+4op7ju3dc y warnings on these products.
1.Ammonia mixed in water forms ammonium hydroxide. State the equation for this process.
2.One concern is that ammonia solutions could mix with acidic cleaning products, such as drain cleaner with sulphuric acid.
1.Determine the balanced equation for ammonium hydroxide reacting with sulphuric acid.
2.Suggest a reason this reaction could be dangerous.

  The function of the acid-base indicator, Innq 7opy*(vd 2m, can be expressed using the equation *m dop n2yv7(qbelow
$In + H_2O \rightleftharpoons InH^+ + OH^-;K_c = 35
Blue Yellow
Which of the below statements are correct?
I.The solution becomes darker blue with the addition of an acid
II.The solution is a pale green at equilibrium
III.$K_c$ increases with the addition of an alkali

In the amino acid glycine, a hydrogen ihk su:v 0tp(d6on may be transferred from one part of the molecule to another as ss6 p(uhvt k:d0hown.



In this reaction, glycine acts as both a Brønsted-Lowry acid and a Brønsted-Lowry base.
1.State the part of the glycine molecule that acts as a Brønsted-Lowry acid in the forward reaction, giving a reason for your answer.
2.In an aqueous solution of glycine, the transfer of the hydrogen ion may involve two reaction steps. The first reaction step is shown.


(i)By considering how a hydrogen ion forms from a hydrogen atom, explain why the hydrogen ion is often referred to as a proton.
(ii)Explain why $H^+$ is not an accurate representation of the cation formed in this reaction.
3.Amino acids such as glycine can be used to produce long molecules called peptides. The shape of the peptide molecule is determined by the types of intermolecular interactions present between the amino acid side chains, which have different structures. Part of a peptide molecule is shown, with the side chains highlighted in bold.


Suggest why acid-base reactions could alter the shape of this peptide chain.

  Which of the following is 3t7(5r8oetp ce fc(eka conjugate acid-base pair?