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习题练习:Mechanisms of Chemical Change F.2 Electron Transfer Reactions



 作者: admin   总分: 39分  得分: _____________

答题人: 匿名未登录  开始时间: 23年12月30日 19:59  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the followi, lifitp.nd:j-h79ks ng statements are correct?
I.Voltaic cells convert chemical energy into electrical energy
II.Electrolytic cells convert electrical energy into chemical energy
III.Electrolytic cells require a salt bridge

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following are the standard conditions for standard cell potend 0,isz *zkb,ofp*3lhtials?o* s3k0zb,pzlh di* f,
I.A temperature of 298K
II.A pressure of 100 kPa
III.Solution concentrations of $1\,mol\,dm{-3}$

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is corrx si2 ie(*je-mect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which row of the table isg0bvw6xo2r0x1e5uh qeidg ): correct for a spontaneous reaction?

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about ela- dip k9n/c/qj ,yqy-e:)v syectrochemical cells is not correct?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What are the correct products of theai;bzozpv g0.u*f+(8/ r ykic reaction of nitric acid and magnesium metal0* vi 8ygrp c;z+bk.u(f/z iao?

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statements about the electrolysis of molten aluminium oxide iq 7 6bdeee/ *jf/4cizare correct?
I. Aluminium ions gain electrons at the cathode
II. Oxide ions lose electrons at the cathode
III. The cathode is the site of reduction in this cell

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8#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which row, indicated in the table below, contains the correct speciesn+a8/evinveh2f;k g +b6a+kwjo xv., that are produced at each electrode duriegj6+iavx + ,wkfk8 ;n/a +2.ehvnobv ng the electrolysis of molten zinc chloride?

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9#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which solution does not produce ox(urm()aofutzy +-;5 hfof 5ub ygen at the anode when electrolyzed with inert electru o-h;(tf)o+ fzfruam( b5 5uyodes?

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Oxygen and water are produced when nitric acid reacts wi: 4buhthu. l.gth potassium manganate(VII)t..4 gubhl:h u,$KMnO_4$.
$4KMnO_4(aq) + 12HNO_3(aq) \rightarrow 6H_2O(I) + 5O_2(g) + 4KNO_3(aq) + 4Mn(NO_3)_2(aq)$
1.Define reduction in terms of electron transfer.
2.State the oxidation state of manganese in $KMnO_4$ and in $Mn(NO_3)_2$.In $KMnO_4$:X=    , In $Mn(NO_3)_2$:X=   
3.Identify which species has been oxidized in this reaction and specify the change in oxidation state it has undergone.

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11#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statements are correct about an eleci mc v0tidzc(bml *am9e) 5;l3trolytic cell?
I. An external power supply is used to drive a non-spontaneous process
II.Oxidation occurs at the positive electrode in the cell
III.The cell could be used to extract a reactive metal from its molten salt

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a vol ,hz569fz4 (vhcw6r nxjl -nxftaic cell. The overall reaction taking place in the cell is: lfcj,hwr n-9xz hz65v6n x(f4
$Mg(s) + Pb^{2+}(aq) \rightarrow Pb(s) + Mg^{2+}(aq)$


Which statement is correct for the magnesium half cell?

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13#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What is the balanced chemical equations6 *0 gcxxj8uo5lv)mm and $E^{\theta}$ cell for the spontaneous reaction between the following half-cells?
$Pb^{2+}(aq) + 2e^- \rightarrow Pb(s)$ -0.13V
$Cu^{2+}(aq) + 2e^- \rightarrow Cu(s)$ +0.34V

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about electroplating an object with silv ) v5y.bdzfkotr/ia51 er is incorrect?

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15#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What happens to the 2i a1)u+cpaid/8u wmo$Mn^{3+}_{(aq)}$ ion when it is converted to $MnO_{4(aq)}^-$

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16#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  A primary alcohol is heated under reflux with an aqueous solu yk5dqfq;;cdk b8+gl) igelp45 )jkv/tion of the oxidizinggdd kig85)p5 /;; )fk +4llbvkjqyqec agent $KMnO_4$Which of the following is a possible product of this reaction?



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17#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Using the voltaic cell notation given below and the standard e90a f/-nh lofwlectrode potentials, determine the standa w0/-flnhof9ard cell potential of the cell,$E^{\Theta}$.
$Pb(s) | Pb^{2+}(aq) || Ag^+(aq) | Ag(s)$
$Ag^+(aq) + e^- \rightarrow Ag(s)$ +0.80V
$Pb^{2+}(aq) 2e^- \rightarrow Pb(s)$ -0.13V

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18#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Using the following half reactions, how many moles of elect/)hja(m(:a psy7kn yprons are transferred in the equation for the o:m7j a((pyn)/y hpaksxidation of ethanol in the presence of acidified potassium dichromate when balanced with whole numbers?
$Cr_2O_7^{2-}(aq) + 14H^+(aq) +6e^- \rightarrow 2Cr^{3+}(aq) + 7H_2O(I)$
$CH_3CH_2OH(aq) + H_2O(I) \rightarrow CH_3COOH(aq) + 4H^+(aq) + 4e^-$

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19#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Electrolysis of $Cu^{2+}$ using a current of 1A for 10s produces x mol of Cu metal.
If Q= It, how many moles of Cu metal is produced if $Cu^+$ is electrolyzed under the same conditions?

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20#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
1.Draw an electrolytic cell for the e)g9bbacs3es q+ srz1 u*:ztmo30p3vq lectrolysis of molten sodium chloride. Label the direction of electron flow and the polarity of the electrcpeb)zg+mo* u9q3:s1tr q33szb vs0aodes.
2. 1.Deduce the major products if dilute aqueous sodium chloride was electrolysed instead.
2.Deduce the major products if concentrated aqueous sodium chloride was electrolysed instead.
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21#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the below reactions shows the oxidabz8vwfud0(bj1 +)8q fvhd 4 uqtion of a secondary alcohol?

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22#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a Daniel c,nl3t dbo61zi ell. Zinc is more reactive than copper. When the cell is operating3 61 nbtlido,z, which statement about the ions in the cell is correct?



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23#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What is the reducing a ac9l3qoa q(u,gent in this reaction?
$Zn_{(s)} + 2NO_{3(aq)}^-$ + 4H^+_{(aq)} \rightarrow Zn^{2+}_{(aq)} + 2NO_{2(g)} + 2H_2O_{(I)}$

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24#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The below diagram shows a;c: yev.sq0gsaur ;)p 6j8hwj cb: .oan electrolytic cell. At which electrode will bromine form, and what is the process taking ; .ashb ;pr gc y:sc6qvuj8a0oe.w:)jplace there?



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25#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a Daniel cell. lth(r ,z0q2g, *b rzy r2d1ttokka51iZinc is more reactive than copper. When the spontaneous reaction occurs, which statement about the Danieo1dhtig tr kt(5*r z 2kbl,ar,yq12z0l cell is correct?



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26#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The equation for the ov (hxru v (5rw d(/ezk5u 0pv2 rn2evyn3iqlm:*erall reaction in a voltaic cell is:
$Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)$
Which statements are correct for this cell?
I. Electrons flow from the copper electrode to the silver electrode
II. Silver ions are reduced in the reaction
III. The copper anode will become smaller in size as the reaction proceeds

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27#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What are the respective oxidation states of t, lqs0(7o ml-/ibh) neje/n xsulfur in the following sulfur-contais q7//e0ml n ,obxinj-( lht)ening species?
$SO_3^{2-}, H_2SO_4, S_8, S_2O_3^{2-}$

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28#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Alkali metals react with water to form metal hydroxipd) (s) zeus17r(sy2nhtk /mz; ydh)bde and hydrogen gas.
1.Write a balanced equation between sodium and water.
2.Explain why this reaction is considered as a redox reaction.
3.3 other alkali metals W, X and Y also react with water.
Based on the following observations, arrange the metals in order, starting from the weakest oxidizing agent. Explain your answer.  $\lt$  $\lt$  $\lt$
MetaObservations
W Slow reaction with water
X Vigorous reaction with water
Y Fast reaction with water


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29#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What happens to nitrogen whenj,7olu q2w5iu3g alo/ nitrate changes to nitrite ?

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30#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
Sodium metal may be obtained commercially from the electrolysis of moltenjgm1r1f9lnm3 sodium chloride in a Downs cell. Thi91nlmj 3gm 1frs cell operates as an electrolytic cell.
1.Describe, using a diagram, the essential components of this electrolytic cell.
2.Suggest why molten sodium metal may be collected from the top of this type of cell.
3.Describe two ways in which current is conducted in an electrolytic cell.
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31#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  A battery is added to a container of molt 3zui rt6jy3j 2llbi/2en $CaBr_{2(l)}$ to create an electrolytic cell, as shown in the diagram below.



1. 1Use section 24 (Section 19- 2025 Syllabus) of your data booklet to identify and write the oxidation and reduction half-reactions.
2.Label the anode and cathode on the diagram above.
3.On the diagram above, label the electrode where calcium metal $(Ca_{(s)})$will appear.
2.A different electrochemical cell is shown below. One half-cell contains a lead metal electrode immersed in 1.0 M $Pb(NO3)_2$ solution. A standard electrode potential table is also shown for elements X, Y, and Z.


Elements Electrode potential
$X^{2+}_{(aq)} + 2e^- \rightarrow X_{(s)}$ $E^{\Theta}$=-1.18V
$Y^+_{(aq)} + 1e^- \rightarrow Y_{(s)}$ $E^{\Theta}$=-0.45V
$Z^{2+}_{(aq)} + 2e^- \rightarrow Z_{(s)}$ $E^{\Theta}$=+0.34V



1.Label the left half-cell of the diagram with the metal that will produce the highest cell potential.
2.Draw an arrow on the diagram indicating the direction of the flow of electrons.
3.Consult section 24 (Section 19- 2025 Syllabus) in your data booklet to calculate the standard cell potential for the diagrammed cell.  V
4.Use metals X, Y, and Z combined with aqueous chloride solutions of metals X, Y, and Z, and write a balanced equation for a reaction that will proceed spontaneously.

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32#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following redox reaction8o/h2 2ogngrhiy z/ ,uwaq56g:
$Cr_2O_7^{2-}(aq) + 14H^+(aq) + 6Ag(s) \rightarrow 2Cr^{3+}(aq) + 7H_2O(l) + 6Ag^+(aq)$
1. 1.Using section 24 (Section 19- 2025 Syllabus) of the data booklet, calculate the standard cell potential.  V
2.Predict, with a reason, whether this reaction is spontaneous or not.
2.Using sections 1 and 2 of the data booklet, calculate the standard Gibbs free energy change in $kJ\,mol^{-1}$.
The standard entropy change for this reaction is $508J\,K^{-1}\,mol^{-1}$
3.Using section 1 of the data booklet, calculate the standard enthalpy change for this reaction in $kJ\,mol^{-1}$.
$\Delta G^{\Theta}$=  $kJ\,mol^{-1}$, $\Delta H^{\Theta}$=  $kJ\,mol^{-1}$

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33#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Daniell Cell is a galvanic cell with a standard cell poten b o0-kincaw j49u 4/g(e )lo-y+gkoaltial of 1.10V.
$Cu^{2+}(aq) + Zn(s) \rightarrow Cu(s) + Zn^{2+}(aq)$
1. 1.Define standard electrode potential.
2.List the features of a standard hydrogen electrode (SHE).
Suppose the SHE is replaced by a MMSE reference electrode with a standard electrode potential of 0.64V.
2. 1.Using section 24 (Section 19- 2025 Syllabus) of the data booklet, calculate the new electrode potentials.Cu(s):  V, Zn(s):  V
2.Using your answers to (b)(i), calculate the new cell potential and comment on this value.$E_{cell}$=  V

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34#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
For each reaction described below, specify* tgxt :r/i8y(ka6chq its type and write its complete balanced chemical equation using the structural formulas ht6 ik:qx*( a tygr8/cof reactants and products.
1.Formation of butane from but-2-ene.
2.Formation of but-2-one from butan-2-ol.
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35#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Titration technique can be used to determinef s*/, vnmc 62onnbol, the percentage of copper present in a sample of copper (I) oxide. The sample is first dissolsnvm,2n/nc*l6 f,ob oved in acidic solution and $Cu^+$ ions are formed. The resulting solution is then titrated against a standard solution of potassium manganate (VII),$KMnO_{4}$. In acidic solution,$MnO^-_4$ reacts with $Cu^+$ to form $Mn^{2+}$ and $Cu^{2+}$ ions.

Titre 1 2 3
Initial burette reading/$cm^3$ 2.00 24.705.00
Final burette reading/$cm^3$ 25.80 48.30 30.60


Mass of copper oxide (I) sample/g 0.7751
Concentration of $KMnO_{4}$ solution/$mol\,dm^{-3}$ $2.375\times10^{-2}$
1.Using Section 24 (Section 19- 2025 Syllabus)of the Data Booklet, write the equation of the redox reaction.
2.Define reducing agent and specify the reducing agent in the reaction.
3.Calculate the number of moles of $MnO^-_4$ that reacted with $Cu^+$.  $cm^3$
4.Deduce the percentage by mass of Cu present in the sample.  %
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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36#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reactions c /rky i5p4j9dinvolving metals and their aqueous nitrate solutionsp/ yi4kcjr 95d:
$XNO_3$ $Y(NO_3)_2$$Z(NO_3)_2$
Metal X No reaction No reaction
Metal Y Grey solid of metal X observed No reaction
Metal ZGrey solid of metal X observed

Pink solid of metal Y observed
Choose the correct order of the metals from the strongest oxidizing agent to the weakest?

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37#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the followine g 5xno69)vbx ywwf.2g reactions:
$Fe(s) + Cu^{2+}(aq) \rightarrow Fe^{2+}(aq) + Cu(s)$
$Fe(s) + 2Ag^+(aq) \rightarrow Fe^{2+}(aq) + 2Ag(s)$
$Zn(s) + Fe^{2+}(aq) \rightarrow Zn^{2+}(aq) + Fe(s)$
$Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)$

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38#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The equation below shows the reaction between conc zgzod:*ub dn84 :y.x4m2ghtq entrated sulfuric acid and potassium iodid*dq8yzbh :.2d: 4zotng 4uxgme.
$8KI(s) + 5H_2SO_4(aq) \rightarrow 4K_2SO_4(aq) + 4l2(g) + H_2S(g) + 4H_2O(l)$
1.State the oxidation state of sulfur in $H_2SO_4$ and $4H_2S$.In $H_2SO_4$, x=    , in $4H_2S$, x=   
2.Write the half equations for the oxidation and reduction reactions.
3.Define oxidizing agent in terms of electrons.
4.Identify the oxidizing agent in the equation.

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39#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following equations:4 ,encnizls 2zigz 5)- -u8tfp
Equation 1:
$2ClO_3^-(aq) + I_2(aq) \rightarrow Cl_2(aq) + 2IO_3^-(aq)$
Equation 2:
$ Cl_2(aq) + 2NaOH(aq) \rightarrow NaCl(aq) + NaClO(aq) + H_2O(l)$
Which statements about these reactions is/are not correct?
I.Iodine is reduced in equation 1
II.Chlorine is reduced only in equation 1
III.Chlorine is oxidized and reduced in equation 2

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