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习题练习:Mechanisms of Chemical Change F.2 Electron Transfer Reactions

 作者: admin   总分: 39分  得分: _____________

答题人: 游客未登录  开始时间: 23年12月30日 19:59  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following statemengh g 3ehtv , 4/bka6y0.rpzh6wts are correct?
I.Voltaic cells convert chemical energy into electrical energy
II.Electrolytic cells convert electrical energy into chemical energy
III.Electrolytic cells require a salt bridge

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following are the standard conditions for str *w+6i7;gibw5v s-w mct2 jbdandard cell potentials?7+i -vg btcw6b* mwj2diwr;5s
I.A temperature of 298K
II.A pressure of 100 kPa
III.Solution concentrations of $1\,mol\,dm{-3}$

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is correc0 vw 0p*hvcr vh.-sv5ht?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which row of the table is correct 12 /k rckta a6u46rm p,sure fa:h*n:jfor a spontaneous reaction?

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about electrochemicaj nx6gt:cx04vl cells is not correct?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What are the correct products of the reaction of nitric acid and magnesium m2 p k0cgvlq5r24n/zh tr r8ab9etal 8q52btzarv 0nkgr29p4h/c rl?

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statements about the electrolysis of molten alumdw6iv-gspm4 0+d(a;a 7 hk ry3ml; zdqinium oxide are correct?
I. Aluminium ions gain electrons at the cathode
II. Oxide ions lose electrons at the cathode
III. The cathode is the site of reduction in this cell

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8#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which row, indicated in the table below, contaio*o dbsf:y 4yo8y2s3tns the correct species that are produced at each electrodey:yo*83dso o2ys t f4b during the electrolysis of molten zinc chloride?

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9#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which solution does not produce oxygen atlh zk4r, :j). pvze1:a5d cb:xrojn9j the anode when electrolyzed with inert elbv a5ezr 9o,r:h:jzn1ld)4.cjkx j p:ectrodes?

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Oxygen and water are produced when nitric acid reacts;g*lf:,zlq.i ewf wk: with potassium manganate(VIIl.wf: *q: ge;wz filk,),$KMnO_4$.
$4KMnO_4(aq) + 12HNO_3(aq) \rightarrow 6H_2O(I) + 5O_2(g) + 4KNO_3(aq) + 4Mn(NO_3)_2(aq)$
1.Define reduction in terms of electron transfer.
2.State the oxidation state of manganese in $KMnO_4$ and in $Mn(NO_3)_2$.In $KMnO_4$:X=    , In $Mn(NO_3)_2$:X=    
3.Identify which species has been oxidized in this reaction and specify the change in oxidation state it has undergone.

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11#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statements are correc6btp-5d6mkw.t x rxt-hw m,) hb03lcc t about an electrolytic cell?
I. An external power supply is used to drive a non-spontaneous process
II.Oxidation occurs at the positive electrode in the cell
III.The cell could be used to extract a reactive metal from its molten salt

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a voltaic cell. Thzy. 3ynu/sf1w e overall reaction taking place in the wz.yy1sf 3 /nucell is:
$Mg(s) + Pb^{2+}(aq) \rightarrow Pb(s) + Mg^{2+}(aq)$


Which statement is correct for the magnesium half cell?

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13#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What is the balanced chabd 33hefa)7m emical equation and $E^{\theta}$ cell for the spontaneous reaction between the following half-cells?
$Pb^{2+}(aq) + 2e^- \rightarrow Pb(s)$ -0.13V
$Cu^{2+}(aq) + 2e^- \rightarrow Cu(s)$ +0.34V

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about electroplatinkm3/ez.qr+- gz* lqkhg an object with silver is incorrect?

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15#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What happens to the 0g2*h0z01gf y2. zlfmz .vg od, flltk$Mn^{3+}_{(aq)}$ ion when it is converted to $MnO_{4(aq)}^-$

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16#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  A primary alcohol is heated under reflux w9b8gn/zou-; ygvii +kith an aqueous solution of the oxidizing a9/vi+obnzyi8ku g;- ggent $KMnO_4$Which of the following is a possible product of this reaction?



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17#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Using the voltaic cell ndx l;amtsr*8;otation given below and the standard electrode potentials, determine the standard cell potential of the cm ;r*dal s8x;tell,$E^{\Theta}$.
$Pb(s) | Pb^{2+}(aq) || Ag^+(aq) | Ag(s)$
$Ag^+(aq) + e^- \rightarrow Ag(s)$ +0.80V
$Pb^{2+}(aq) 2e^- \rightarrow Pb(s)$ -0.13V

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18#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Using the following half reactions, how many moles of electrj qe fdi;vp/1qhuz:p 3* fkl97ons are transferred in the equation for the oxidation of ethanol in the pre7fp /3jlu1:9; p f*qhkqdvizesence of acidified potassium dichromate when balanced with whole numbers?
$Cr_2O_7^{2-}(aq) + 14H^+(aq) +6e^- \rightarrow 2Cr^{3+}(aq) + 7H_2O(I)$
$CH_3CH_2OH(aq) + H_2O(I) \rightarrow CH_3COOH(aq) + 4H^+(aq) + 4e^-$

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19#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Electrolysis of $Cu^{2+}$ using a current of 1A for 10s produces x mol of Cu metal.
If Q= It, how many moles of Cu metal is produced if $Cu^+$ is electrolyzed under the same conditions?

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20#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
1.Draw an electrolytic cell for the electrolysis of molten sodium chloride. s5i ,uo x -r)qrg/a:waLabel the direction of electron flow and the polarity of the el-w,r ar5x u aso/:q)giectrodes.
2. 1.Deduce the major products if dilute aqueous sodium chloride was electrolysed instead.
2.Deduce the major products if concentrated aqueous sodium chloride was electrolysed instead.
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21#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the below reactions shows the oxidation of a second djwa1 x+tmnfs8w+ 1j7ary alcohol?

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22#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a Daniel cell. Zinc is more reactive than copper. Whenky:zaq/ k tmg vf11m494ny b5p the cell is operating, which staz1:v1 yk4bpg 5ntm 9q4fkaym/ tement about the ions in the cell is correct?



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23#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What is the reducing agent in this (duw.ze02ia1k) 3 **99fiwe3icw lurrfmavfreaction?
$Zn_{(s)} + 2NO_{3(aq)}^-$ + 4H^+_{(aq)} \rightarrow Zn^{2+}_{(aq)} + 2NO_{2(g)} + 2H_2O_{(I)}$

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24#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The below diagram shows an electrolytic q++y ,e (oou/v tysl9tl7 1qs7g)iitvcell. At which electrode will bromine form, and what is q7 g7 qyv 1t +ttll,oueo9(isysi v+)/the process taking place there?



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25#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a Dani(z2i war9b:mlel cell. Zinc is more reactive than copper. When the spontaneous re:r(w9 a2mzlbiaction occurs, which statement about the Daniel cell is correct?



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26#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The equation for the overall reaction in a y7ge+ppfg* (f voltaic cell is:
$Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)$
Which statements are correct for this cell?
I. Electrons flow from the copper electrode to the silver electrode
II. Silver ions are reduced in the reaction
III. The copper anode will become smaller in size as the reaction proceeds

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27#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What are the respective oxidation states of sulfur in the following snd,m- irf 7i;evg 8oe-ulfur-contaimvgifre n-, -ie o87d;ning species?
$SO_3^{2-}, H_2SO_4, S_8, S_2O_3^{2-}$

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28#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Alkali metals react with water t.ab t6p(j4hzs sm vd6:o form metal hydroxide and hydrogen gas.
1.Write a balanced equation between sodium and water.
2.Explain why this reaction is considered as a redox reaction.
3.3 other alkali metals W, X and Y also react with water.
Based on the following observations, arrange the metals in order, starting from the weakest oxidizing agent. Explain your answer.  $\lt$  $\lt$  $\lt$
MetaObservations
W Slow reaction with water
X Vigorous reaction with water
Y Fast reaction with water


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29#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What happens to nitrogen when nitrate changevf j9es5d;, mds to nitrite ?

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30#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
Sodium metal may be obtaingtmmv 80 (m8gje h,dsg.l(3yeed commercially from the electrolysis of molten sodium chloride in a Downs cell. This cell operates as an electes(3dm(t8 ygh8,e . ml gvg0mjrolytic cell.
1.Describe, using a diagram, the essential components of this electrolytic cell.
2.Suggest why molten sodium metal may be collected from the top of this type of cell.
3.Describe two ways in which current is conducted in an electrolytic cell.
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31#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  A battery is added to a container of moltkxdnf3t;/g:.t3)shth7hkjf8g 3t u r en $CaBr_{2(l)}$ to create an electrolytic cell, as shown in the diagram below.



1. 1Use section 24 (Section 19- 2025 Syllabus) of your data booklet to identify and write the oxidation and reduction half-reactions.
2.Label the anode and cathode on the diagram above.
3.On the diagram above, label the electrode where calcium metal $(Ca_{(s)})$will appear.
2.A different electrochemical cell is shown below. One half-cell contains a lead metal electrode immersed in 1.0 M $Pb(NO3)_2$ solution. A standard electrode potential table is also shown for elements X, Y, and Z.


Elements Electrode potential
$X^{2+}_{(aq)} + 2e^- \rightarrow X_{(s)}$ $E^{\Theta}$=-1.18V
$Y^+_{(aq)} + 1e^- \rightarrow Y_{(s)}$ $E^{\Theta}$=-0.45V
$Z^{2+}_{(aq)} + 2e^- \rightarrow Z_{(s)}$ $E^{\Theta}$=+0.34V



1.Label the left half-cell of the diagram with the metal that will produce the highest cell potential.
2.Draw an arrow on the diagram indicating the direction of the flow of electrons.
3.Consult section 24 (Section 19- 2025 Syllabus) in your data booklet to calculate the standard cell potential for the diagrammed cell.  V
4.Use metals X, Y, and Z combined with aqueous chloride solutions of metals X, Y, and Z, and write a balanced equation for a reaction that will proceed spontaneously.

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32#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following redox hd84;ensb-pwqr7h ; greaction:
$Cr_2O_7^{2-}(aq) + 14H^+(aq) + 6Ag(s) \rightarrow 2Cr^{3+}(aq) + 7H_2O(l) + 6Ag^+(aq)$
1. 1.Using section 24 (Section 19- 2025 Syllabus) of the data booklet, calculate the standard cell potential.  V
2.Predict, with a reason, whether this reaction is spontaneous or not.
2.Using sections 1 and 2 of the data booklet, calculate the standard Gibbs free energy change in $kJ\,mol^{-1}$.
The standard entropy change for this reaction is $508J\,K^{-1}\,mol^{-1}$
3.Using section 1 of the data booklet, calculate the standard enthalpy change for this reaction in $kJ\,mol^{-1}$.
$\Delta G^{\Theta}$=  $kJ\,mol^{-1}$, $\Delta H^{\Theta}$=  $kJ\,mol^{-1}$

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33#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Daniell Cell is a galvanic cell with a standard cell potential v0en6mq: ay,r of 1.10V.
$Cu^{2+}(aq) + Zn(s) \rightarrow Cu(s) + Zn^{2+}(aq)$
1. 1.Define standard electrode potential.
2.List the features of a standard hydrogen electrode (SHE).
Suppose the SHE is replaced by a MMSE reference electrode with a standard electrode potential of 0.64V.
2. 1.Using section 24 (Section 19- 2025 Syllabus) of the data booklet, calculate the new electrode potentials.Cu(s):  V, Zn(s):  V
2.Using your answers to (b)(i), calculate the new cell potential and comment on this value.$E_{cell}$=  V

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34#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
For each reaction described below, specify its type and write its compl5 ys7:m eh5cejete balanced chemical equation using the structural fo mc5 :h5sjey7ermulas of reactants and products.
1.Formation of butane from but-2-ene.
2.Formation of but-2-one from butan-2-ol.
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35#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Titration technique can be used t);f+tfdd815*bga 7b aru-qxk9h ik wdue vg)0o determine the percentage of copper present in a sample of copper (I) oxide. The sample is first dissolved in aci8 aqgg15 ; vkxb fd-ftu0)*wdahb)r+9d7e ukidic solution and $Cu^+$ ions are formed. The resulting solution is then titrated against a standard solution of potassium manganate (VII),$KMnO_{4}$. In acidic solution,$MnO^-_4$ reacts with $Cu^+$ to form $Mn^{2+}$ and $Cu^{2+}$ ions.

Titre 1 2 3
Initial burette reading/$cm^3$ 2.00 24.705.00
Final burette reading/$cm^3$ 25.80 48.30 30.60


Mass of copper oxide (I) sample/g 0.7751
Concentration of $KMnO_{4}$ solution/$mol\,dm^{-3}$ $2.375\times10^{-2}$
1.Using Section 24 (Section 19- 2025 Syllabus)of the Data Booklet, write the equation of the redox reaction.
2.Define reducing agent and specify the reducing agent in the reaction.
3.Calculate the number of moles of $MnO^-_4$ that reacted with $Cu^+$.  $cm^3$
4.Deduce the percentage by mass of Cu present in the sample.  %
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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36#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reactions involving metals and 40 l pzg1fz3uyf30hav2 zi ad7their aqueous nitrate solutions: ah 0 3ad7p3z4z0gyf lu21zivf
$XNO_3$ $Y(NO_3)_2$$Z(NO_3)_2$
Metal X No reaction No reaction
Metal Y Grey solid of metal X observed No reaction
Metal ZGrey solid of metal X observed

Pink solid of metal Y observed
Choose the correct order of the metals from the strongest oxidizing agent to the weakest?

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37#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reactiont fs;fv fmh;y uv7wn4zq11xf;)9 -x sts:
$Fe(s) + Cu^{2+}(aq) \rightarrow Fe^{2+}(aq) + Cu(s)$
$Fe(s) + 2Ag^+(aq) \rightarrow Fe^{2+}(aq) + 2Ag(s)$
$Zn(s) + Fe^{2+}(aq) \rightarrow Zn^{2+}(aq) + Fe(s)$
$Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)$

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38#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The equation below shows the reaction between concentrated sull5zl 4jq3s3(zhb5 l-mmo/ .qjs:,k yywnc; bm furic acid and potassium i/m:y j.yl3o m ,5mzlqn zwhl bc-;b3sk4(jq s5odide.
$8KI(s) + 5H_2SO_4(aq) \rightarrow 4K_2SO_4(aq) + 4l2(g) + H_2S(g) + 4H_2O(l)$
1.State the oxidation state of sulfur in $H_2SO_4$ and $4H_2S$.In $H_2SO_4$, x=    , in $4H_2S$, x=    
2.Write the half equations for the oxidation and reduction reactions.
3.Define oxidizing agent in terms of electrons.
4.Identify the oxidizing agent in the equation.

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39#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following equations: f1c bme*(y e x9d59hs 0amwn,o
Equation 1:
$2ClO_3^-(aq) + I_2(aq) \rightarrow Cl_2(aq) + 2IO_3^-(aq)$
Equation 2:
$ Cl_2(aq) + 2NaOH(aq) \rightarrow NaCl(aq) + NaClO(aq) + H_2O(l)$
Which statements about these reactions is/are not correct?
I.Iodine is reduced in equation 1
II.Chlorine is reduced only in equation 1
III.Chlorine is oxidized and reduced in equation 2

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