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习题练习:Mechanisms of Chemical Change F.2 Electron Transfer Reactions



 作者: admin   总分: 39分  得分: _____________

答题人: 匿名未登录  开始时间: 23年12月30日 19:59  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following sqk x+dbx1bo y+0af4w .tatements are correct?
I.Voltaic cells convert chemical energy into electrical energy
II.Electrolytic cells convert electrical energy into chemical energy
III.Electrolytic cells require a salt bridge

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following are the standard conditions for standard eysm ff64k3 yux39c t/cell potentials? 6yfu y4cf3 xk sme/3t9
I.A temperature of 298K
II.A pressure of 100 kPa
III.Solution concentrations of $1\,mol\,dm{-3}$

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is corrq p5s 4/)vbder)3x5 t:pz7qr +fzfqio7wa2l uect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which row of the table is correct for a spontaneous,2+y-0 i0qxd;l- ki qrrxaoti reaction?

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about electrochemical cells is not 6ciet w xvvf)2/eg;vh nmqc u:.+qa-:correct?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What are the correct promi oe5mq,fv. ;2(k4djou)g eaducts of the reaction of nitric acid and magnesium metal?)gk av2iuom(oe,qdmje45; f.

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statements about the eleqnu-, 6eqn2ejcxw96 fyy a u21ctrolysis of molten aluminium oxide are correct?
I. Aluminium ions gain electrons at the cathode
II. Oxide ions lose electrons at the cathode
III. The cathode is the site of reduction in this cell

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8#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which row, indicated in the table below, contains the correl1/)1hkx ow 7ss/z u+h, bjjn;yi/gtyct species that are produced atzhj;/x+1 7os/gb/ )w,jsktilyyhun 1 each electrode during the electrolysis of molten zinc chloride?

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9#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which solution does not produce oxygen at the anode when electrolyzed with iner5vs8fdbda ,r txqc sev 8z-s7l5: q m--mf.k1ot ,cx5 1sek z:d8o 8svm qtla- 5.qmbv7 ff--sdrelectrodes?

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Oxygen and water are produced when (go,hia j.v13cy3gq unitric acid reacts with potassium manganate(Vac,hg j 3ogy.3qu(vi1II),$KMnO_4$.
$4KMnO_4(aq) + 12HNO_3(aq) \rightarrow 6H_2O(I) + 5O_2(g) + 4KNO_3(aq) + 4Mn(NO_3)_2(aq)$
1.Define reduction in terms of electron transfer.
2.State the oxidation state of manganese in $KMnO_4$ and in $Mn(NO_3)_2$.In $KMnO_4$:X=    , In $Mn(NO_3)_2$:X=    
3.Identify which species has been oxidized in this reaction and specify the change in oxidation state it has undergone.

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11#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statements are corr.ma k:bg8v5conq50k eect about an electrolytic cell?
I. An external power supply is used to drive a non-spontaneous process
II.Oxidation occurs at the positive electrode in the cell
III.The cell could be used to extract a reactive metal from its molten salt

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a volt5bz kj4g*57vgj7ffxd aic cell. The overall reaction taking place in the c4gb jf dk77zfgv*55 jxell is:
$Mg(s) + Pb^{2+}(aq) \rightarrow Pb(s) + Mg^{2+}(aq)$


Which statement is correct for the magnesium half cell?

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13#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What is the balanced chemical equation .jgdq1b; c7 , c0orjprand $E^{\theta}$ cell for the spontaneous reaction between the following half-cells?
$Pb^{2+}(aq) + 2e^- \rightarrow Pb(s)$ -0.13V
$Cu^{2+}(aq) + 2e^- \rightarrow Cu(s)$ +0.34V

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about electroplating an object with sil w*zwxi6ldufmr,-dc k72 c9x0ver is incorrect?

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15#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What happens to the hk295fegn*irbd n k1.$Mn^{3+}_{(aq)}$ ion when it is converted to $MnO_{4(aq)}^-$

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16#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  A primary alcohol is heated under reflux with an aqueous s d:emb8-h0kag olution of the oxidizing habk-0 eg: 8mdagent $KMnO_4$Which of the following is a possible product of this reaction?



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17#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Using the voltaic cell notation given below and the standardoo1 trw,tbc rn,u,x yo80-akq +ch 2x: electrode potentials, determine the standard cell potenokwcu8r xc0t2a:,qr+ oh,b 1t-x, noytial of the cell,$E^{\Theta}$.
$Pb(s) | Pb^{2+}(aq) || Ag^+(aq) | Ag(s)$
$Ag^+(aq) + e^- \rightarrow Ag(s)$ +0.80V
$Pb^{2+}(aq) 2e^- \rightarrow Pb(s)$ -0.13V

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18#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Using the following half reactions, how many moles of electro4 iba47z 8 qnmnssq()ans are transferred in the equation for thess 4n8bz74 a)mq q(ain oxidation of ethanol in the presence of acidified potassium dichromate when balanced with whole numbers?
$Cr_2O_7^{2-}(aq) + 14H^+(aq) +6e^- \rightarrow 2Cr^{3+}(aq) + 7H_2O(I)$
$CH_3CH_2OH(aq) + H_2O(I) \rightarrow CH_3COOH(aq) + 4H^+(aq) + 4e^-$

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19#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Electrolysis of $Cu^{2+}$ using a current of 1A for 10s produces x mol of Cu metal.
If Q= It, how many moles of Cu metal is produced if $Cu^+$ is electrolyzed under the same conditions?

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20#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
1.Draw an electrolytic cell for the electrolysis of molten sodium chl . onzomiu+o)0oride. Label the direction of electron flow and the polarity of the elect.zon i+o)mo 0urodes.
2. 1.Deduce the major products if dilute aqueous sodium chloride was electrolysed instead.
2.Deduce the major products if concentrated aqueous sodium chloride was electrolysed instead.
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21#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the below reactions shows the oxidatidejh nn3;oz+xt a 53 7slhi8le3sd1 2con of a secondary alcohol?

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22#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a Daniela0 wmh1 hw4 8+amrtl.t cell. Zinc is more reactive than copper. When the cell is operating, which statement about the ions in the cell is corrm1athl w 0.mt arw+4h8ect?



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23#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What is the reducing agc79lpf .6jxm uent in this reaction?
$Zn_{(s)} + 2NO_{3(aq)}^-$ + 4H^+_{(aq)} \rightarrow Zn^{2+}_{(aq)} + 2NO_{2(g)} + 2H_2O_{(I)}$

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24#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The below diagram shows annlr* 4 vbr4rp/ electrolytic cell. At which electrode will bromine form, and what is the process taking place there? nl4 /vr4*rbpr



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25#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a Daniel cell. Zinc is more reactive than copper. When,bse m x-3dd1ot i+e;i the spontaneous reaction occurs, which statem3 tix e1od isb-e;+,dment about the Daniel cell is correct?



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26#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The equation for the overall reaction in a voltaic cni,ml f ;cepq4 mh1k9 q(dm7r o8)hd7tell is:
$Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)$
Which statements are correct for this cell?
I. Electrons flow from the copper electrode to the silver electrode
II. Silver ions are reduced in the reaction
III. The copper anode will become smaller in size as the reaction proceeds

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27#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What are the respective oxidation states of sulfur in the follaz1luu34bx;v *k i p/aowing sulfur-contain1au b4k;alv3/ p* uxizing species?
$SO_3^{2-}, H_2SO_4, S_8, S_2O_3^{2-}$

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28#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Alkali metals react wp4 7e+9cwmq* ee tuzx6ith water to form metal hydroxide and hydrogen gas.
1.Write a balanced equation between sodium and water.
2.Explain why this reaction is considered as a redox reaction.
3.3 other alkali metals W, X and Y also react with water.
Based on the following observations, arrange the metals in order, starting from the weakest oxidizing agent. Explain your answer.  $\lt$  $\lt$  $\lt$
MetaObservations
W Slow reaction with water
X Vigorous reaction with water
Y Fast reaction with water


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29#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What happens to nitrogen when nitryy u4ph3,/-u1uy + q;s7 xwcydn)wkznate changes to nitrite ?

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30#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
Sodium metal may be obtained commercially from the electrolysis of molten sodi fyuo )hytjz*:94dt2u . t8+um+krl-g jzjah1 um chloride in a Downs j* lzrmhg y4u++j duo8az.1f tt-hk:t9y2ju )cell. This cell operates as an electrolytic cell.
1.Describe, using a diagram, the essential components of this electrolytic cell.
2.Suggest why molten sodium metal may be collected from the top of this type of cell.
3.Describe two ways in which current is conducted in an electrolytic cell.
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31#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  A battery is added to a container o6,bkv6,fxu2, mdto 4t rbi mo/f molten $CaBr_{2(l)}$ to create an electrolytic cell, as shown in the diagram below.



1. 1Use section 24 (Section 19- 2025 Syllabus) of your data booklet to identify and write the oxidation and reduction half-reactions.
2.Label the anode and cathode on the diagram above.
3.On the diagram above, label the electrode where calcium metal $(Ca_{(s)})$will appear.
2.A different electrochemical cell is shown below. One half-cell contains a lead metal electrode immersed in 1.0 M $Pb(NO3)_2$ solution. A standard electrode potential table is also shown for elements X, Y, and Z.


Elements Electrode potential
$X^{2+}_{(aq)} + 2e^- \rightarrow X_{(s)}$ $E^{\Theta}$=-1.18V
$Y^+_{(aq)} + 1e^- \rightarrow Y_{(s)}$ $E^{\Theta}$=-0.45V
$Z^{2+}_{(aq)} + 2e^- \rightarrow Z_{(s)}$ $E^{\Theta}$=+0.34V



1.Label the left half-cell of the diagram with the metal that will produce the highest cell potential.
2.Draw an arrow on the diagram indicating the direction of the flow of electrons.
3.Consult section 24 (Section 19- 2025 Syllabus) in your data booklet to calculate the standard cell potential for the diagrammed cell.  V
4.Use metals X, Y, and Z combined with aqueous chloride solutions of metals X, Y, and Z, and write a balanced equation for a reaction that will proceed spontaneously.

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32#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following redndb 9 zw8.0iezox reaction:
$Cr_2O_7^{2-}(aq) + 14H^+(aq) + 6Ag(s) \rightarrow 2Cr^{3+}(aq) + 7H_2O(l) + 6Ag^+(aq)$
1. 1.Using section 24 (Section 19- 2025 Syllabus) of the data booklet, calculate the standard cell potential.  V
2.Predict, with a reason, whether this reaction is spontaneous or not.
2.Using sections 1 and 2 of the data booklet, calculate the standard Gibbs free energy change in $kJ\,mol^{-1}$.
The standard entropy change for this reaction is $508J\,K^{-1}\,mol^{-1}$
3.Using section 1 of the data booklet, calculate the standard enthalpy change for this reaction in $kJ\,mol^{-1}$.
$\Delta G^{\Theta}$=  $kJ\,mol^{-1}$, $\Delta H^{\Theta}$=  $kJ\,mol^{-1}$

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33#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Daniell Cell is a galvanic cell with a standa8yk 4zk-ll-hl-a 6wvx rd cell potential of 1.10V.
$Cu^{2+}(aq) + Zn(s) \rightarrow Cu(s) + Zn^{2+}(aq)$
1. 1.Define standard electrode potential.
2.List the features of a standard hydrogen electrode (SHE).
Suppose the SHE is replaced by a MMSE reference electrode with a standard electrode potential of 0.64V.
2. 1.Using section 24 (Section 19- 2025 Syllabus) of the data booklet, calculate the new electrode potentials.Cu(s):  V, Zn(s):  V
2.Using your answers to (b)(i), calculate the new cell potential and comment on this value.$E_{cell}$=  V

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34#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
For each reaction described below, specify its type and write its complete baly:a u 26khmcv:anced chemical equation using the structuralcy vu:ahkm2 :6 formulas of reactants and products.
1.Formation of butane from but-2-ene.
2.Formation of but-2-one from butan-2-ol.
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35#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Titration technique can be used to determine the percentage of copper pr-vnugn:+h n hj.7:.cjtuywl, 5u )ya4huse;o esent in a sample of copper (I) oxide. The sc +n4,7 y;uwtln:-5ouh sga v.ehuu ) ny:.jhjample is first dissolved in acidic solution and $Cu^+$ ions are formed. The resulting solution is then titrated against a standard solution of potassium manganate (VII),$KMnO_{4}$. In acidic solution,$MnO^-_4$ reacts with $Cu^+$ to form $Mn^{2+}$ and $Cu^{2+}$ ions.

Titre 1 2 3
Initial burette reading/$cm^3$ 2.00 24.705.00
Final burette reading/$cm^3$ 25.80 48.30 30.60


Mass of copper oxide (I) sample/g 0.7751
Concentration of $KMnO_{4}$ solution/$mol\,dm^{-3}$ $2.375\times10^{-2}$
1.Using Section 24 (Section 19- 2025 Syllabus)of the Data Booklet, write the equation of the redox reaction.
2.Define reducing agent and specify the reducing agent in the reaction.
3.Calculate the number of moles of $MnO^-_4$ that reacted with $Cu^+$.  $cm^3$
4.Deduce the percentage by mass of Cu present in the sample.  %
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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36#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reactions involving metals and their 4v)c -gxf+bbq.d+oe r aqueous nitrate solutions: vgexqdc-b++ b4or .)f
$XNO_3$ $Y(NO_3)_2$$Z(NO_3)_2$
Metal X No reaction No reaction
Metal Y Grey solid of metal X observed No reaction
Metal ZGrey solid of metal X observed

Pink solid of metal Y observed
Choose the correct order of the metals from the strongest oxidizing agent to the weakest?

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37#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reactions:* zs6mvjs-p mr 0sx2s3
$Fe(s) + Cu^{2+}(aq) \rightarrow Fe^{2+}(aq) + Cu(s)$
$Fe(s) + 2Ag^+(aq) \rightarrow Fe^{2+}(aq) + 2Ag(s)$
$Zn(s) + Fe^{2+}(aq) \rightarrow Zn^{2+}(aq) + Fe(s)$
$Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)$

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38#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The equation below shows the react.n o) b3 1tegi997fpi u25g rntm5kj6po ylin9ion between concentrated sulfuric acid and potassium iodidn 59t i)mgp 61i2flg iopnoru.t7y95 bkn3 9jee.
$8KI(s) + 5H_2SO_4(aq) \rightarrow 4K_2SO_4(aq) + 4l2(g) + H_2S(g) + 4H_2O(l)$
1.State the oxidation state of sulfur in $H_2SO_4$ and $4H_2S$.In $H_2SO_4$, x=    , in $4H_2S$, x=    
2.Write the half equations for the oxidation and reduction reactions.
3.Define oxidizing agent in terms of electrons.
4.Identify the oxidizing agent in the equation.

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39#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following equatrfw cwv,, 8zl)ions:
Equation 1:
$2ClO_3^-(aq) + I_2(aq) \rightarrow Cl_2(aq) + 2IO_3^-(aq)$
Equation 2:
$ Cl_2(aq) + 2NaOH(aq) \rightarrow NaCl(aq) + NaClO(aq) + H_2O(l)$
Which statements about these reactions is/are not correct?
I.Iodine is reduced in equation 1
II.Chlorine is reduced only in equation 1
III.Chlorine is oxidized and reduced in equation 2

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