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习题练习:What Drives Chemical Reactions D.4 Entropy and Spontaneity



 作者: admin   总分: 14分  得分: _____________

答题人: 匿名未登录  开始时间: 23年07月23日 17:22  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following reactions will have the q2hza ;si 0tx 83zvm*z;/sjw lgreatest decrease in entropy?

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following combinations of ΔH and ΔS results in the jkxm- y 7q/.nmmost spontaneous 7 /qnyxmj-m.kreaction at 298 K?

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following statements about entropy is in9dvq5 b0 fpys3- bdpmb9ku 50ecorrect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following compounds are arranged in order /no)+jkm66.zgpp8ch ge) jw y of decreasing entropy?

C(s)
H2O(l)
O2
CO2(g)
>

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is true for an endothermic reaction.8z0 x(c nfvdg/f2z uv that results in an increase in entroduxf 0nz.28 fc(/g zvvpy?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about the relationship between Gidm,:a - 6rtskybbs free energy change and the equilibrium constant is corrk-6tdm rs: ,ayect?

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following factorslafwf*-mkkpv 2/j ; 5;) hkolh affect the entropy of a system containing gases? h/ l f;fjak2vmh*k5l)k;-w po
I. The temperature of the system
II. The states of the system
III. The pressure of the system

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8#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Gibbs free energy change can be used to determine the9+t( cvdbj ;3y/7 agz/ cjc:n3phq9qmouli r6 spontaneity of a react(z r3vutimqcqdpn/63;7bg:cj h+9y ajlc o9 / ion.
1.1.Define Gibbs free energy change of formation.
1.2.Define spontaneous reaction.

2.1.State a correctly balanced equation that represents the complete combustion of butane.

2.2.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the Gibbs free energy change of this reaction.
ΔGreaction=-  kJ mol1
2.3.State, with a reason, whether this reaction is spontaneous or not.

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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9#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Methanol is produced by reacting carbon monoxide and hydrogen according to the fhm of- e77cf f.2+)kw;rujmp) exv7)bnej4ugollowinmmfpunu 7 h-j27e .exw7r)o4)+cv)kf;eg fbjg reaction:
CO(g)+2H2(g)CH3OH(g)
CO(g)+2H2(g)CH3OH(g)
1.Deduce the equilibrium constant expression for the formation of methanol.
At 500C ,a 750cm3 sealed flask is found to contain 0.923 mol of CH_3OH, 0.352mol of CO and 0.124 mol of H2.
2.1.Calculate the value of Kc at 500 C. Kc 
2.2.Using sections 1 and 2 of the data booklet, calculate ΔGθ at 500 C.
T=  K;ΔGθ=-  kJ mol1

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Ethanol can be produced through the fermentation of glucosev)n ypk037d nx:
C6H12O6(aq)→2C2H5OH(l)+2CO2(g)
1.1.Predict whether the entropy change for this reaction is positive or negative. Explain your reasoning.
1.2.The absolute entropy for glucose is +209.2 J K1 mol1.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change for this reaction.
ΔSreaction=+  JK1 mol1

2.The enthalpy of formation of glucose is -1273.3kJ mol1.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the enthalpy change for this reaction.
ΔHreaction=-  kJ mol1

3.Using your answers to (a)(ii) and (b), calculate the Gibbs free energy change at 298K.
ΔG=-  kJ mol1
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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11#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Dry ice, solid CO2,is commonly used as a cooling or freezing agent in the medical and food industries.
1.Write an equation representing the sublimation of CO2.
2.The enthalpy of sublimation for CO2 is +26.1kJ mol1 and the absolute entropy of CO2 in the solid state is 51.1 J K1 mol1.
2.1.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change associated with the sublimation of CO2.
ΔSreaction=+  J K1 mol1
2.2.Using your answer to (bi), calculate the Gibbs free energy change for the sublimation of CO2 at K.
ΔG=-  kJ mol1

3.Calculate the minimum temperature at which CO2 sublimates.
T>  K

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  How does Gibbs free en ,ah1ds*p ;x6gppphrk 46gj+dergy relate to chemical equilibrium?

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13#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following re7ustp y5v i8.p+heb;z action:
C2H4(g)+H2(g)→C2H6(g)
ΔH is -136kJ mol1
ΔS is -121jk1 mol1
ΔG at 298K is -99.9kJ mol1
1.1.Explain why the enthalpy of formation of H2 is 0 kJ mol1.
1.2.Explain why the entropy change for this reaction is negative.

2.Explain how a reaction can be spontaneous with a negative entropy change.

3.Calculate the temperature at which this reaction is no longer spontaneous.
T=  K

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The following graph shows the Gibbs free energy against the edmd) sttj70, kxtent of reaction for a ret)jk ,tmsd 70dversible reaction.
At what point is the reaction at equilibrium?




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