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习题练习:What Drives Chemical Reactions D.4 Entropy and Spontaneity



 作者: admin   总分: 14分  得分: _____________

答题人: 匿名未登录  开始时间: 23年07月23日 17:22  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following react ryv7-1 ;mnifrions will have the greatest decrease in entropy?

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following combinations of ΔH and p+q8n hitmqo32wx3z2z9uw b,ΔS results in the most spontaneous reacu p293z8nqq wz mi,ob2ht +w3xtion at 298 K?

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following statements aih- no18ozqh.bout entropy is incorrect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following compounds are arranged in order of decy4ubf1kpzy 62 reasing entropy?

$C$(s)
$H_2O$(l)
$O_2$
$CO_2$(g)
>

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is true for an endothermi9tzs.c/: vwk t, (clkic reaction that results in an increase in entropy?(lz 9cvsc tiw/ k,.tk:

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about the relationship between Gibbs frfv3*f3 v0 kw j bbpd,h*ua8nip3 h*o0cee energy change and the equilibrium constant is corrb jkoi,u dhfpf*n300 8p*vabwc33v h*ect?

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following factors affect the entropy of am1rm 79 s7/*nv;3qtyakbotno4 l4p qq system containing gases? s7/ 1oya3mt;4vrqq *k4mtol97b n nqp
I. The temperature of the system
II. The states of the system
III. The pressure of the system

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8#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Gibbs free energy change can be useof(i ipf4+etgp vqz0rbs(; 054 fq- ywd to determine the spontaneity of a reaction. o(yzi4q i 4rf(qtv ; -w5fpge0s 0p+fb
1.1.Define Gibbs free energy change of formation.
1.2.Define spontaneous reaction.

2.1.State a correctly balanced equation that represents the complete combustion of butane.

2.2.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the Gibbs free energy change of this reaction.
ΔG$_{reaction}$=-  kJ mol$^{-1}$
2.3.State, with a reason, whether this reaction is spontaneous or not.

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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9#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Methanol is produced by reac87.jtel4arrur2/vyy mbpm2)/5 csyyting carbon monoxide and hydrogen according to the following ra)y/trm.rb2up yc8yj54vl7ye m2 /s r eaction:
$CO(g)$+2$H_2(g)$ → $CH_3OH$(g)
$CO(g)$+2$H_2(g)$ ← $CH_3OH$(g)
1.Deduce the equilibrium constant expression for the formation of methanol.
At 500$^{\circ}C$ ,a 750cm$^3$ sealed flask is found to contain 0.923 mol of CH_3OH, 0.352mol of CO and 0.124 mol of $H_2$.
2.1.Calculate the value of K$_c$ at 500 $^{\circ}C$. K$_c$=  
2.2.Using sections 1 and 2 of the data booklet, calculate ΔG$^θ$ at 500 $^{\circ}C$.
T=  K;ΔG$^θ$=-  kJ mol$^{-1}$

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Ethanol can be produced through the fermentation of gl/lx+k7dqjh7 uo3q z oe1k*366gar iuhucose:
$C_6H_12O_6$(aq)→2$C_2H_5OH$(l)+2$CO_2$(g)
1.1.Predict whether the entropy change for this reaction is positive or negative. Explain your reasoning.
1.2.The absolute entropy for glucose is +209.2 J K$^{-1}$ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change for this reaction.
ΔS$_{reaction}$=+  JK$^{-1}$ mol$^{-1}$

2.The enthalpy of formation of glucose is -1273.3kJ mol$^{-1}$.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the enthalpy change for this reaction.
ΔH$_{reaction}$=-  kJ mol$^{-1}$

3.Using your answers to (a)(ii) and (b), calculate the Gibbs free energy change at 298K.
ΔG=-  kJ mol$^{-1}$
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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11#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Dry ice, solid $CO_2$,is commonly used as a cooling or freezing agent in the medical and food industries.
1.Write an equation representing the sublimation of $CO_2$.
2.The enthalpy of sublimation for $CO_2$ is +26.1kJ mol$^{-1}$ and the absolute entropy of $CO_2$ in the solid state is 51.1 J K$^{-1}$ mol$^{-1}$.
2.1.Using section 12 (Section 13- 2025 Syllabus) of the data booklet, calculate the entropy change associated with the sublimation of $CO_2$.
ΔS$_{reaction}$=+  J K$^{-1}$ mol$^{-1}$
2.2.Using your answer to (bi), calculate the Gibbs free energy change for the sublimation of $CO_2$ at K.
ΔG=-  kJ mol$^{-1}$

3.Calculate the minimum temperature at which $CO_2$ sublimates.
T>  K

Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  How does Gibbs free energy relate to chemical equx tl ,s9.bcy1xf*pctt,y w1 f;ilibrium?

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13#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reacgzx3w4c m (zx6akf3k5eep3 k6tion:
$C_2H_4$(g)+$H_2$(g)→$C_2H_6$(g)
ΔH is -136kJ mol$^{-1}$
ΔS is -121jk$^{-1}$ mol$^{-1}$
ΔG at 298K is -99.9kJ mol$^{-1}$
1.1.Explain why the enthalpy of formation of $H_2$ is 0 kJ mol$^{-1}$.
1.2.Explain why the entropy change for this reaction is negative.

2.Explain how a reaction can be spontaneous with a negative entropy change.

3.Calculate the temperature at which this reaction is no longer spontaneous.
T=  K

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The following graph shows the Gibbs free energy against the extenk l *l266n9t bfp2awry4jho,v t of reaction fj 2,h wptl*6bl4yan ro6 f92kvor a reversible reaction.
At what point is the reaction at equilibrium?




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