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习题练习:Mechanisms of Chemical Change F.2 Electron Transfer Reactions



 作者: admin   总分: 39分  得分: _____________

答题人: 匿名未登录  开始时间: 23年12月30日 19:59  切换到: 整卷模式

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1#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following statementsc7p;gyfw 32olz 22, hjol*nvv1x 3hn x are correct?
I.Voltaic cells convert chemical energy into electrical energy
II.Electrolytic cells convert electrical energy into chemical energy
III.Electrolytic cells require a salt bridge

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2#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the following are the standard conditions for standard cuy ,c iy -0eclz;ho)xc*gw3lf3th5)o ell potentials? 5ihl ) -3*cwo), f c3czhtueo0xyy;gl
I.A temperature of 298K
II.A pressure of 100 kPa
III.Solution concentrations of $1\,mol\,dm{-3}$

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3#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement is codu)5y6z qv wsg )pjq:ma 67oj8rrect?

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4#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which row of the table is cor4 oeh4j:i(qf l.cynq.+v dha 2t7ty*m rect for a spontaneous reaction?

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5#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about electrochemical cells iu0 :y;i :7jk5r ag3vc:r 9skn:fgm,d jv; ivuqs not correct?

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6#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What are the correct products of the reaction of nitric acid and magnesium re:/ hmkx39kmesd.bx)o7 k .h metal?h9)ex7x .d :sobkmmk er.h3 /k

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7#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statements about the electrolysis of molten aluminium oxide are correct? gojdvl;:s4 1v
I. Aluminium ions gain electrons at the cathode
II. Oxide ions lose electrons at the cathode
III. The cathode is the site of reduction in this cell

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8#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which row, indicated in the table below, xq2:ztv 7hxl cob:+;(mla g9jcontains the correct species that are produced at eacchmlq +t2 ::zx9g;o7lxa(vbjh electrode during the electrolysis of molten zinc chloride?

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9#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which solution does not produce oxygen at the anode when electrolyzed wij f, qlezuw25(tb)-xec9gdk3th inert electck2e(du)bzt j5we9 3 x, lfq-grodes?

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10#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Oxygen and water are produced when nitric acid reacts with potassium manganate(Vfx2i1),cnf+ 2myx ypeII)fx+,yf2 i xecn p1my2),$KMnO_4$.
$4KMnO_4(aq) + 12HNO_3(aq) \rightarrow 6H_2O(I) + 5O_2(g) + 4KNO_3(aq) + 4Mn(NO_3)_2(aq)$
1.Define reduction in terms of electron transfer.
2.State the oxidation state of manganese in $KMnO_4$ and in $Mn(NO_3)_2$.In $KMnO_4$:X=    , In $Mn(NO_3)_2$:X=    
3.Identify which species has been oxidized in this reaction and specify the change in oxidation state it has undergone.

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11#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statements are1aftyqlse s 9q 2c(r*/ correct about an electrolytic cell?
I. An external power supply is used to drive a non-spontaneous process
II.Oxidation occurs at the positive electrode in the cell
III.The cell could be used to extract a reactive metal from its molten salt

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12#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a voltaic cell. The overall reaction takinc4eo sfv71v u0g place in the cell is: 1ucf4 eov7v0s
$Mg(s) + Pb^{2+}(aq) \rightarrow Pb(s) + Mg^{2+}(aq)$


Which statement is correct for the magnesium half cell?

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13#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What is the balanced chemical equation and ;pw0tt zah u,+9 dgcs)$E^{\theta}$ cell for the spontaneous reaction between the following half-cells?
$Pb^{2+}(aq) + 2e^- \rightarrow Pb(s)$ -0.13V
$Cu^{2+}(aq) + 2e^- \rightarrow Cu(s)$ +0.34V

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14#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which statement about electropm bgkii6 swy a8t3;g)+v.1mnflating an object with silver is incorrect?

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15#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What happens to the (etu:b *ac/f)m o+ 8vxmgh gb:$Mn^{3+}_{(aq)}$ ion when it is converted to $MnO_{4(aq)}^-$

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16#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  A primary alcohol is heated under reflux with an aqueous soluti+rg1k zy yz3u7on of the oxidizing ag1zzryk 7y+u g3ent $KMnO_4$Which of the following is a possible product of this reaction?



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17#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Using the voltaic cell notation given below and the standard electrode potentiaqg21q w3rtqz) ls, determine the standard cell potr1 t2g wq3qz)qential of the cell,$E^{\Theta}$.
$Pb(s) | Pb^{2+}(aq) || Ag^+(aq) | Ag(s)$
$Ag^+(aq) + e^- \rightarrow Ag(s)$ +0.80V
$Pb^{2+}(aq) 2e^- \rightarrow Pb(s)$ -0.13V

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18#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Using the following half reab *8lhwn :snnxgoxa 88 e49yz/ctions, how many moles of electrons are transferred in the equation for the oxidation of ethanol in the presence of acidified po8 8h*4nn9wxb8/g snlxoza :ey tassium dichromate when balanced with whole numbers?
$Cr_2O_7^{2-}(aq) + 14H^+(aq) +6e^- \rightarrow 2Cr^{3+}(aq) + 7H_2O(I)$
$CH_3CH_2OH(aq) + H_2O(I) \rightarrow CH_3COOH(aq) + 4H^+(aq) + 4e^-$

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19#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Electrolysis of $Cu^{2+}$ using a current of 1A for 10s produces x mol of Cu metal.
If Q= It, how many moles of Cu metal is produced if $Cu^+$ is electrolyzed under the same conditions?

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20#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
1.Draw an electrolytic cell for the electrolysis of molten sodium chloride. La2uwkz uf x+3w53bjdu 7l5ic)sbel the direction of electron flow j5wwbk +s) di23fulxz573ucu and the polarity of the electrodes.
2. 1.Deduce the major products if dilute aqueous sodium chloride was electrolysed instead.
2.Deduce the major products if concentrated aqueous sodium chloride was electrolysed instead.
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21#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Which of the below reactions shoq/twb7d3vb)r ws the oxidation of a secondary alcohol?

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22#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a Daniel cell. Zin8iwpxz9 .u0l zc is more reactive than copper. When the cell is operating, which statement about the ions in the cell is correct? l8izwp z0 9xu.



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23#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What is the reducing agent in this reaction)6i y ji f /y01farwvetfbqj6 ;4)q.mw?
$Zn_{(s)} + 2NO_{3(aq)}^-$ + 4H^+_{(aq)} \rightarrow Zn^{2+}_{(aq)} + 2NO_{2(g)} + 2H_2O_{(I)}$

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24#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The below diagram shows an electrolytic cell. At which electrode wil2 f f n:)bkh;u/nes0wbl bromine form, and what is the process taking place th)0nu:fnh; ks/2 bb wfeere?



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25#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The diagram below shows a Daniel cell. Zinc is more reactive than c+s)ajsj 4s:xlfk 2h ;nopper. When the spontaneous reaction occurs, which statement about the Dash nj:4; )ls k2sjfa+xniel cell is correct?



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26#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The equation for the overall reaction in a voltaisd6cc;.uk n1dc cell is:
$Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)$
Which statements are correct for this cell?
I. Electrons flow from the copper electrode to the silver electrode
II. Silver ions are reduced in the reaction
III. The copper anode will become smaller in size as the reaction proceeds

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27#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What are the respective orwsf.o v5: ,0mf ff2erxidation states of sulfur in the following sulfur-containing sper: f.5m2rw, ef 0fvofscies?
$SO_3^{2-}, H_2SO_4, S_8, S_2O_3^{2-}$

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28#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Alkali metals react with water to form metal (,4i whxfg6(bbji9 hb qfa19mhydroxide and hydrogen gas.
1.Write a balanced equation between sodium and water.
2.Explain why this reaction is considered as a redox reaction.
3.3 other alkali metals W, X and Y also react with water.
Based on the following observations, arrange the metals in order, starting from the weakest oxidizing agent. Explain your answer.  $\lt$  $\lt$  $\lt$
MetaObservations
W Slow reaction with water
X Vigorous reaction with water
Y Fast reaction with water


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29#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  What happens to nitrogen when nitrate changes to nitrite 4(uw v)4b3e e7tidtin?

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30#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
Sodium metal may be obtained commercially from the electrolysis of-q)ef4 nhzcgcc, 9zi)qyr u)1 molten sodium chloride in a Do z)gy4r ,eucq1h9q)cz- c) nifwns cell. This cell operates as an electrolytic cell.
1.Describe, using a diagram, the essential components of this electrolytic cell.
2.Suggest why molten sodium metal may be collected from the top of this type of cell.
3.Describe two ways in which current is conducted in an electrolytic cell.
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31#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  A battery is added to sndou3av 5q45 a container of molten $CaBr_{2(l)}$ to create an electrolytic cell, as shown in the diagram below.



1. 1Use section 24 (Section 19- 2025 Syllabus) of your data booklet to identify and write the oxidation and reduction half-reactions.
2.Label the anode and cathode on the diagram above.
3.On the diagram above, label the electrode where calcium metal $(Ca_{(s)})$will appear.
2.A different electrochemical cell is shown below. One half-cell contains a lead metal electrode immersed in 1.0 M $Pb(NO3)_2$ solution. A standard electrode potential table is also shown for elements X, Y, and Z.


Elements Electrode potential
$X^{2+}_{(aq)} + 2e^- \rightarrow X_{(s)}$ $E^{\Theta}$=-1.18V
$Y^+_{(aq)} + 1e^- \rightarrow Y_{(s)}$ $E^{\Theta}$=-0.45V
$Z^{2+}_{(aq)} + 2e^- \rightarrow Z_{(s)}$ $E^{\Theta}$=+0.34V



1.Label the left half-cell of the diagram with the metal that will produce the highest cell potential.
2.Draw an arrow on the diagram indicating the direction of the flow of electrons.
3.Consult section 24 (Section 19- 2025 Syllabus) in your data booklet to calculate the standard cell potential for the diagrammed cell.  V
4.Use metals X, Y, and Z combined with aqueous chloride solutions of metals X, Y, and Z, and write a balanced equation for a reaction that will proceed spontaneously.

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32#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following redox uqoud mcpe(t+x 1p09( reaction:
$Cr_2O_7^{2-}(aq) + 14H^+(aq) + 6Ag(s) \rightarrow 2Cr^{3+}(aq) + 7H_2O(l) + 6Ag^+(aq)$
1. 1.Using section 24 (Section 19- 2025 Syllabus) of the data booklet, calculate the standard cell potential.  V
2.Predict, with a reason, whether this reaction is spontaneous or not.
2.Using sections 1 and 2 of the data booklet, calculate the standard Gibbs free energy change in $kJ\,mol^{-1}$.
The standard entropy change for this reaction is $508J\,K^{-1}\,mol^{-1}$
3.Using section 1 of the data booklet, calculate the standard enthalpy change for this reaction in $kJ\,mol^{-1}$.
$\Delta G^{\Theta}$=  $kJ\,mol^{-1}$, $\Delta H^{\Theta}$=  $kJ\,mol^{-1}$

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33#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The Daniell Cell is a galvanic cell with k x:i0n sn4pc9qe:e*ua standard cell potential of 1.10V.
$Cu^{2+}(aq) + Zn(s) \rightarrow Cu(s) + Zn^{2+}(aq)$
1. 1.Define standard electrode potential.
2.List the features of a standard hydrogen electrode (SHE).
Suppose the SHE is replaced by a MMSE reference electrode with a standard electrode potential of 0.64V.
2. 1.Using section 24 (Section 19- 2025 Syllabus) of the data booklet, calculate the new electrode potentials.Cu(s):  V, Zn(s):  V
2.Using your answers to (b)(i), calculate the new cell potential and comment on this value.$E_{cell}$=  V

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34#
 
问答题 ( 1.0 分) 切至整卷模式 搜藏此题  
For each reaction described below, specify its type and write its complzv*g lp6ng0 yb28a0 egete balanced chemical e yb*6pav0n2ggl80z ge quation using the structural formulas of reactants and products.
1.Formation of butane from but-2-ene.
2.Formation of but-2-one from butan-2-ol.
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35#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Titration technique can be used to determine the percentag25kna)4+ yt/ wijcu uuj exm(osk1) ,ge of copper present in a sample of copper (I) oxide. The say i )esgukjwa(/u4) + t1knmux cj,o52mple is first dissolved in acidic solution and $Cu^+$ ions are formed. The resulting solution is then titrated against a standard solution of potassium manganate (VII),$KMnO_{4}$. In acidic solution,$MnO^-_4$ reacts with $Cu^+$ to form $Mn^{2+}$ and $Cu^{2+}$ ions.

Titre 1 2 3
Initial burette reading/$cm^3$ 2.00 24.705.00
Final burette reading/$cm^3$ 25.80 48.30 30.60


Mass of copper oxide (I) sample/g 0.7751
Concentration of $KMnO_{4}$ solution/$mol\,dm^{-3}$ $2.375\times10^{-2}$
1.Using Section 24 (Section 19- 2025 Syllabus)of the Data Booklet, write the equation of the redox reaction.
2.Define reducing agent and specify the reducing agent in the reaction.
3.Calculate the number of moles of $MnO^-_4$ that reacted with $Cu^+$.  $cm^3$
4.Deduce the percentage by mass of Cu present in the sample.  %
Important note: The section numbers mentioned in the video solution are specific to the 2024 syllabus.
You can refer to the question stem to find the section numbers in the 2025 syllabus.

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36#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following reacniw s6 c.89gzmept ;q),a ez5ctions involving metals and their aqueous nitrate solutions:9,wnz6 z5.eem isp )g;qa t8cc
$XNO_3$ $Y(NO_3)_2$$Z(NO_3)_2$
Metal X No reaction No reaction
Metal Y Grey solid of metal X observed No reaction
Metal ZGrey solid of metal X observed

Pink solid of metal Y observed
Choose the correct order of the metals from the strongest oxidizing agent to the weakest?

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37#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following react49;b n2wkwhc1 q7 shiaions:
$Fe(s) + Cu^{2+}(aq) \rightarrow Fe^{2+}(aq) + Cu(s)$
$Fe(s) + 2Ag^+(aq) \rightarrow Fe^{2+}(aq) + 2Ag(s)$
$Zn(s) + Fe^{2+}(aq) \rightarrow Zn^{2+}(aq) + Fe(s)$
$Cu(s) + 2Ag^+(aq) \rightarrow Cu^{2+}(aq) + 2Ag(s)$

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38#
 
填空题 ( 1.0 分) 切至整卷模式 搜藏此题  
  The equation below shows the reaction between concentratekbdq znx9(o1.d sulfuric acid and potassi zxko(.dnq91b um iodide.
$8KI(s) + 5H_2SO_4(aq) \rightarrow 4K_2SO_4(aq) + 4l2(g) + H_2S(g) + 4H_2O(l)$
1.State the oxidation state of sulfur in $H_2SO_4$ and $4H_2S$.In $H_2SO_4$, x=    , in $4H_2S$, x=    
2.Write the half equations for the oxidation and reduction reactions.
3.Define oxidizing agent in terms of electrons.
4.Identify the oxidizing agent in the equation.

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39#
 
单选题 ( 1.0 分) 切至整卷模式 搜藏此题  
  Consider the following eu z5 b6ma9(slzt;yq h/quations:
Equation 1:
$2ClO_3^-(aq) + I_2(aq) \rightarrow Cl_2(aq) + 2IO_3^-(aq)$
Equation 2:
$ Cl_2(aq) + 2NaOH(aq) \rightarrow NaCl(aq) + NaClO(aq) + H_2O(l)$
Which statements about these reactions is/are not correct?
I.Iodine is reduced in equation 1
II.Chlorine is reduced only in equation 1
III.Chlorine is oxidized and reduced in equation 2

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